1258278-95-3

Basic information

• Product Name: bis(3-bromonaphthalen-2-yl)methanol
• Synonyms: bis(3-bromonaphthalen-2-yl)methanol
• CAS NO: 1258278-95-3
• Molecular Weight: 442.15
• Mol File: 1258278-95-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(3-bromonaphthalen-2-yl)methanol(CAS DataBase Reference)
• NIST Chemistry Reference: bis(3-bromonaphthalen-2-yl)methanol(1258278-95-3)
• EPA Substance Registry System: bis(3-bromonaphthalen-2-yl)methanol(1258278-95-3)

Safety Data

• Hazardous Substances Data: 1258278-95-3(Hazardous Substances Data)

Upstream product

• 13214-70-5 2,3-dibromonaphthalene 
• 89005-11-8 3-bromo-2-naphthalenecarboxaldehyde 

Relevant articles and documents

Synthesis and comparative characterization of 9-boraanthracene, 5-boranaphthacene, and 6-borapentacene stabilized by the H2IMes carbene

A general procedure for the preparation of three N-heterocyclic carbene stabilized, boron-containing acenes (9-boraanthracene, 5-boranaphthacene, and 6-borapentacene) is presented. The key steps involve a transmetallation reaction between BCl3 and an appropriate stannacyclic precursor, and the dehydrochlorination of the H2IMes adduct of the chloroborane product. Comparative structural, photophysical, and redox properties reveal narrow HOMO-LUMO gaps relative to the all-carbon acene analogues. Just add boron: Synthetic routes to the N-heterocyclic-carbene-stabilized 5-boranaphthacene and 6-borapentacene are described and complement that previously developed for 9-boraanthracene. Comparative structural, photophysical, and redox properties reveal narrow HOMO-LUMO gaps relative to the all-carbon acene analogues.