bis(3-bromonaphthalen-2-yl)methanol

Base Information

• Chemical Name: bis(3-bromonaphthalen-2-yl)methanol
• CAS No.: 1258278-95-3
• Molecular Formula: C₂₁H₁₄Br₂O
• Molecular Weight: 442.15
• Mol file: 1258278-95-3.mol

Synonyms:bis(3-bromonaphthalen-2-yl)methanol

Chemical Property of bis(3-bromonaphthalen-2-yl)methanol

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of bis(3-bromonaphthalen-2-yl)methanol

There total 1 articles about bis(3-bromonaphthalen-2-yl)methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

2,3-dibromonaphthalene (13214-70-5) + 3-bromo-2-naphthalenecarboxaldehyde (89005-11-8) → bis(3-bromonaphthalen-2-yl)methanol (1258278-95-3)

Guidance literature:

2,3-dibromonaphthalene; With TurboGrignard; In tetrahydrofuran; at 0 ℃; Inert atmosphere;

3-bromo-2-naphthalenecarboxaldehyde; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1002/chem.201001922

Reference yield: 97.0%

methyl 4-phenylbenzoate (720-75-2) + bis(3-bromonaphthalen-2-yl)methanol (1258278-95-3) → 6-([1,1'-biphenyl]-4-yl)pentacene

Guidance literature:

bis(3-bromonaphthalen-2-yl)methanol; With magnesium; In tetrahydrofuran; at 20 ℃; for 12h; Inert atmosphere; Reflux;

methyl 4-phenylbenzoate; In tetrahydrofuran; at 20 ℃; for 4h; Inert atmosphere;

DOI:10.1002/anie.201505414

Reference yield: 90.0%

bis(3-bromonaphthalen-2-yl)methanol (1258278-95-3) + benzyl bromide (100-39-0) → C28H20Br2O

Guidance literature:

bis(3-bromonaphthalen-2-yl)methanol; With sodium hydride; potassium iodide; In tetrahydrofuran; mineral oil; for 0.5h; Inert atmosphere;

benzyl bromide; In tetrahydrofuran; mineral oil; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1021/acs.orglett.0c01775

upstream raw materials:

2,3-dibromonaphthalene

3-bromo-2-naphthalenecarboxaldehyde

Refernces