89005-11-8Relevant articles and documents
ORGANIC SEMICONDUCTOR AND MANUFACTURING METHOD THEREOF
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Paragraph 0290; 0291; 0292; 0293, (2019/04/26)
The organic semiconductor of the present invention comprises a strain type compound represented by the following formula (1). (In the formula, Z represents an atom selected from group 13 to 16 elements in the periodic table rings A 1 and A 2 are rings having at least one carbon-carbon unsaturated bond R 1a , R 1b and R 2 are the same or different and each represents a hydrogen atom or a substituent R 3 represents an atom selected from the group 16 element in the periodic table R A and R B are the same or different and each represents a hydrogen atom, a substituent or an atom selected from the group 16 element in the periodic table m represents an integer of 0 to 4 n represents an integer of 0 to 2 p1 and p2 each represents an integer of 0 or more andrepresents a single bond or a double bond). The organic semiconductor has high mobility (electrical mobility) and can be easily or efficiently molded by a wet process such as coating.
Synthesis and comparative characterization of 9-boraanthracene, 5-boranaphthacene, and 6-borapentacene stabilized by the H2IMes carbene
Wood, Thomas K.,Piers, Warren E.,Keay, Brian A.,Parvez, Masood
supporting information; experimental part, p. 12199 - 12206 (2011/02/25)
A general procedure for the preparation of three N-heterocyclic carbene stabilized, boron-containing acenes (9-boraanthracene, 5-boranaphthacene, and 6-borapentacene) is presented. The key steps involve a transmetallation reaction between BCl3 and an appropriate stannacyclic precursor, and the dehydrochlorination of the H2IMes adduct of the chloroborane product. Comparative structural, photophysical, and redox properties reveal narrow HOMO-LUMO gaps relative to the all-carbon acene analogues. Just add boron: Synthetic routes to the N-heterocyclic-carbene-stabilized 5-boranaphthacene and 6-borapentacene are described and complement that previously developed for 9-boraanthracene. Comparative structural, photophysical, and redox properties reveal narrow HOMO-LUMO gaps relative to the all-carbon acene analogues.
A Simple Method of Generating Naphthofuran and Naphthofuran
Smith, James G.,Dibble, Peter W.,Sandborn, Richard E.
, p. 1197 - 1198 (2007/10/02)
Naphthofuran and the novel naphthofuran have been generated from 2-(hydroxymethyl)-1-naphthaldehyde and 3-(hydroxymethyl)-2-naphthaldehyde, respectively, and trapped in Diels-Alder reactions with maleic anhydride.