Products Categories
Basic Information
| CAS No.: | 619-50-1 |
|---|---|
| Name: | Methyl 4-nitrobenzoate |
| Article Data: | 445 |
| Molecular Structure: | |
|
|
|
| Formula: | C8H7NO4 |
| Molecular Weight: | 181.148 |
| Synonyms: | Benzoicacid, p-nitro-, methyl ester (6CI,8CI);4-Methoxycarbonylnitrobenzene;4-nitrobenzoic acid methyl ester;Methyl 4-nitrobenzoate;Methylp-nitrobenzoate;NSC 4137;p-Carbomethoxynitrobenzene;p-Nitrobenzoic acidmethyl ester; |
| EINECS: | 210-599-2 |
| Density: | 1.301 g/cm3 |
| Melting Point: | 94-96 °C(lit.) |
| Boiling Point: | 302.6 °C at 760 mmHg |
| Flash Point: | 149.2 °C |
| Appearance: | light yellow to yellow fine crystalline powder |
| Safety: | 22-24/25 |
| PSA: | 72.12000 |
| LogP: | 1.90460 |
Related products
- 81281-59-67-Benzylideneaminotheophylline
- 82993-81-5D-threo-Ritalinic acid hydrochloride
- 73441-42-6METHYL-5-CHLORO-2,2-DIMETHYLVALERATE
- 68439-39-4Poly(oxy-1,2-ethanediyl), alpha-(2-ethylhexyl)-omega-hydroxy-,
- 852475-26-4MC1568
- 958254-66-51H-Imidazo[4,5-b]pyridine-2-carboxaldehyde, 1-methyl-, hydrochloride
- 99170-93-1N-Methyl-2-oxazolamine
- 717878-06-31-(4-fluorophenyl)-4-nitro-1H-imidazole
- 914458-26-7[5-(2-fluorophenyl)-1-pentyl-1H-pyrrol-3-yl]-1-naphthalenyl-Methanone
- 894852-01-87-BROMO-2,2-DIMETHYL-2H-PYRIDO[3,2-B][1,4]OXAZIN-3(4H)-ONE
Synthetic route
Conditions
| Conditions | Yield |
|---|---|
| With dmap; 2-chloro-1-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododecyl)pyridinium trifluoromethanesulfonate; triethylamine In N,N-dimethyl-formamide at 20℃; for 1h; | 100% |
| Stage #1: 4-nitro-benzoic acid With 1H-imidazole; iodine; triphenylphosphine In dichloromethane at 20℃; for 0.0833333h; Garegg-Samuelsson type reaction; Stage #2: methanol In dichloromethane at 20℃; Garegg-Samuelsson type reaction; | 100% |
| With dmap; 2-chloro-1-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-henicosafluorododecyl)pyridinium trifluoromethanesulfonate; triethylamine In N,N-dimethyl-formamide at 20℃; for 1h; | 100% |
- 636-98-6
p-nitrobenzene iodide
- 201230-82-2
carbon monoxide
- 1067-21-6
triethylmethoxystannane
- 619-50-1
4-nitrobenzoic acid methyl ester
Conditions
| Conditions | Yield |
|---|---|
| With iodophenylbis(triphenylphosphine)palladium under 760 Torr; for 1h; | 100% |
...Expand
- 18107-18-1
diazomethyl-trimethyl-silane
- 62-23-7
4-nitro-benzoic acid
- 619-50-1
4-nitrobenzoic acid methyl ester
Conditions
| Conditions | Yield |
|---|---|
| In methanol; toluene at 20℃; for 2h; | 100% |
| In ethyl acetate | 60% |
| In methanol; diethyl ether; hexane at 20℃; for 2h; Inert atmosphere; | 178 mg |
- 5564-73-8
1-(dimethoxymethyl)pyrrolidine
- 62-23-7
4-nitro-benzoic acid
- 619-50-1
4-nitrobenzoic acid methyl ester
Conditions
| Conditions | Yield |
|---|---|
| In 1,2-dichloro-ethane at 30℃; for 25h; | 100% |
- 67-56-1
methanol
A
- 619-50-1
4-nitrobenzoic acid methyl ester
B
- 154109-07-6
diethyl [N-(hydroxy)imino](p-fluorophenyl)methylphosphonate
Conditions
| Conditions | Yield |
|---|---|
| for 6h; Inert atmosphere; Reflux; | A 100% B 100% |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| With water; iodine; sodium nitrite at 20 - 70℃; chemoselective reaction; | 99% |
| With ammonium peroxydisulfate at 60℃; for 2.5h; | 99% |
| With potassium hydroxide; iodine at 0℃; for 0.0166667h; | 98% |
Conditions
| Conditions | Yield |
|---|---|
| With sodium carbonate; palladium; silver(l) oxide at 80℃; for 48h; Molecular sieve; | 99% |
| With dihydrogen peroxide for 3h; Irradiation; | 95% |
| With oxygen; potassium carbonate at 60℃; under 750.075 Torr; for 20h; | 94% |
Conditions
| Conditions | Yield |
|---|---|
| scandium tris(trifluoromethanesulfonate) at 64℃; for 168h; | 98% |
| With dipotassium hydrogenphosphate for 5h; Reflux; | 98% |
| With potassium ethoxide | |
| acrylonitrile; triphenylphosphine at 25℃; for 24h; | 71 % Chromat. |
Conditions
| Conditions | Yield |
|---|---|
| In benzene for 3h; Heating; | 98% |
| In benzene Product distribution; Mechanism; Heating; other nucleophiles; var. reaction conditions; | 98% |
| In benzene for 3h; Mechanism; Heating; | 98% |
Conditions
| Conditions | Yield |
|---|---|
| magnesium(II) perchlorate In nitromethane at 40℃; for 16h; | 98% |
| With 2,6-dimethylpyridine; fac-tris(2-phenylpyridinato-N,C2')iridium(III) In N,N-dimethyl-formamide at 20℃; for 48h; Sealed tube; Inert atmosphere; Irradiation; |
Post a RFQ
1
What can I do for you?
Get Best Price
Get Best Price for 619-50-1
Methyl 4-nitrobenzoate
Chemistry
MF: C8H7NO4
MW: 181.15
EINECS: 210-599-2
METHYL-p-NITROBENZOATE,it's melting point is about 94-96 °C(lit.);It's appearance is white or yellow crystal.Soluble in ethanol, Ether, Chloroform, insoluble in water.
Following is the molecular structure of METHYL-p-NITROBENZOATE:
MW: 181.15
EINECS: 210-599-2
METHYL-p-NITROBENZOATE,it's melting point is about 94-96 °C(lit.);It's appearance is white or yellow crystal.Soluble in ethanol, Ether, Chloroform, insoluble in water.
Following is the molecular structure of METHYL-p-NITROBENZOATE:
Toxicity Data With Reference
| 1. | ipr-mus LD50:200 mg/kg | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) No. AD691-490 . |
RTECS : DH5775000
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of NOx.
Safety Statements: 22-24/25 (Do not breathe dust;Avoid contact with skin and eyes )
WGK Germany: 3
Safety Statements: 22-24/25 (Do not breathe dust;Avoid contact with skin and eyes )
WGK Germany: 3