Basic Information | Post buying leads | Suppliers | Cas Database |
Name |
Diethylamine hydrochloride |
EINECS | 211-541-9 |
CAS No. | 660-68-4 | Density | 1.0 g/mL at 20 °C |
PSA | 12.03000 | LogP | 1.80870 |
Solubility | soluble in water | Melting Point |
227-230 °C(lit.) |
Formula | C4H11N.HCl | Boiling Point | 57.3 °C at 760 mmHg |
Molecular Weight | 109.599 | Flash Point | 320-330°C |
Transport Information | UN 1993 3/PG 3 | Appearance | white to off-white crystals or crystalline powder |
Safety | 26-39-7-24/25-36 | Risk Codes | 10-36/37/38 |
Molecular Structure | Hazard Symbols | Xn,Xi | |
Synonyms |
Diethyl ammonium chloride;Di-Ethyl Amine Hydrochloride;Diethylammonium chloride;Ethanamine, N-ethyl-, hydrochloride;diethyl amine hydrochloride;N-Ethylethanamine hydrochloride;diethylazanium chloride;N-ethylethanamine; |
Article Data | 96 |
Conditions | Yield |
---|---|
With hydroxylamine hydrochloride In ethanol for 2h; Reflux; | 100% |
With methanol; acetyl chloride In diethyl ether at 0℃; for 1h; Inert atmosphere; | 93% |
N-hydroxy-4-methylbenzenecarboximidoyl chloride
diethylamine
A
diethyl amine hydrochloride
B
N,N-Diethyl-N'-hydroxy-4-methyl-benzamidine
Conditions | Yield |
---|---|
In diethyl ether for 48h; Ambient temperature; | A n/a B 99% |
diethylamine
4-nitrobenzohydroximoyl chloride
A
diethyl amine hydrochloride
B
N,N-Diethyl-N'-hydroxy-4-nitro-benzamidine
Conditions | Yield |
---|---|
In diethyl ether for 48h; Ambient temperature; | A n/a B 99% |
Conditions | Yield |
---|---|
In aq. buffer pH=4 - 7.4; pH-value; Irradiation; | A 99% B 99% |
B
diethyl amine hydrochloride
Conditions | Yield |
---|---|
With hydrogenchloride In pentane Under stirring a strong stream of hydrogenhalogenide is bubbled for 20 min through the soln. of phosphine complex at room temp.(inert atmosphere).; Solvent is evapd. at room temp. in vac., residue is digested with pentane, dialkylamminhydrohalogenide is filtered off, filtrate is dried to dryness in vac., chromy., elem. anal.; | A 98% B n/a |
B
diethyl amine hydrochloride
Conditions | Yield |
---|---|
With hydrogenchloride In pentane Under stirring a strong stream of hydrogenhalogenide is bubbled for 3-10 min through the cooled (-50-0°C) soln. of phosphine complex (inert atmosphere).; Solvent is evapd. at room temp. in vac., residue is digested with pentane, dialkylamminhydrohalogenide is filtered off, filtrate is dried to dryness in vac., recrystn. from pentane (-78°C), not purely isolated.; | A 96% B n/a |
bis(diethylamino)phenylphosphine(pentacarbonyl)molybdenum(0)
A
chlorodiethylaminophenylphosphine(pentacarbonyl)molybdenum(0)
B
diethyl amine hydrochloride
Conditions | Yield |
---|---|
With hydrogenchloride In benzene Under stirring a strong stream of hydrogenhalogenide is bubbled for 10 min through the cooled (0°C) soln. of phosphine complex (inert atmosphere).; Solvent is evapd. at room temp. in vac., residue is digested with pentane, dialkylamminhydrohalogenide is filtered off, filtrate is dried to dryness in vac., recrystn. from pentane (-78°C), elem. anal.; | A 95% B n/a |
bis(diethylamino)phenylphosphine(pentacarbonyl)tungsten(0)
A
chlorodiethylaminophenylphosphine(pentacarbonyl)tungsten(0)
B
diethyl amine hydrochloride
Conditions | Yield |
---|---|
With hydrogenchloride In pentane Under stirring a strong stream of hydrogenhalogenide is bubbled for 3-10 min through the cooled (-50-0°C) soln. of phosphine complex (inert atmosphere).; Solvent is evapd. at room temp. in vac., residue is digested with pentane, dialkylamminhydrohalogenide is filtered off, filtrate is dried to dryness in vac., recrystn. from pentane (-78°C), not purely isolated.; | A 93% B n/a |
trichlorotris(tetrahydrofuran)molybdenum(III)
trimethylsilylazide
diethylammonium O,O-dimethyl phosphorodithioate
[MoN(S2P(OCH3)2)2]4
B
diethyl amine hydrochloride
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: (CH3)3SiCl; (N2); mixt. of complex/(CH3)3SiN3/THF warmed at 45-50°C for 1 h,evapd., (C2H5)2NH2(S2P(OCH3)2) and THF added, stirred for 3 h; concd., filtered, filtrate treated with MeOH, concd., MeOH added, ppt. filtered, washed with MeOH, dried, recrystd. (MeOH/THF); elem. anal.; | A 61% B 93% |
4-phenylpiperidine
di-tert-butyl dicarbonate
A
diethyl amine hydrochloride
B
tert-butyl 4-phenylpiperidine-1-carboxylate
Conditions | Yield |
---|---|
With diethylamine In 1,2-dichloro-ethane at 20℃; | A n/a B 90.6% |
1. | orl-rat LD50:9900 mg/kg | GISAAA Gigiena i Sanitariya. 49 (1)(1984),71. | ||
2. | orl-mus LD50:4860 mg/kg | GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 31 (1)(1987),49. | ||
3. | ipr-mus LD50:960 mg/kg | JJPAAZ Japanese Journal of Pharmacology. 17 (1967),475. | ||
4. | scu-mus LD50:1130 mg/kg | AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. 112 (1957),36. | ||
5. | ivn-mus LD50:320 mg/kg | AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. 112 (1957),36. |
Poison by intravenous route. Moderately toxic by subcutaneous and intraperitoneal routes. When heated to decomposition it emits toxic fumes of NOx, NH3, and HCl.
Safety Information of Diethylammonium Chloride(660-68-4)
Hazard Codes Xn,Xi
Risk Statements 10-36/37/38
10 Flammable
36/37/38 Irritating to eyes, respiratory system and skin
Safety Statements 26-39-7-24/25-36
RIDADR UN 1993 3/PG 3
WGK Germany 3
RTECS SP5740000
F 21
HS Code 29211200