87413-09-0Relevant articles and documents
An Improved Procedure for the Preparation of the Dess-Martin Periodinane
Ireland, Robert E.,Liu, Longbin
, p. 2899 (1993)
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Preparation method of DMP (Dess-Martin periodinane)
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Paragraph 0038; 0039; 0041; 0044; 0054; 0058, (2019/01/13)
The invention discloses a preparation method of a DMP (Dess-Martin periodinane). The target product DMP is obtained through two steps of reactions with 2-iodobenzoic acid, potassium hydrogen persulfate, glacial acetic acid, acetic anhydride and the like as raw materials. The process is convenient and stable, the product is easy to separate and high in yield, the method is environmentally friendly,the comprehensive yield is 82% or above, the raw materials are cheap and easy to obtain, and industrial mass production is facilitated.
The crystal structure of the Dess-Martin periodinane
Schroeckeneder, Albert,Stichnoth, Desiree,Mayer, Peter,Trauner, Dirk
, p. 1523 - 1527,5 (2020/09/14)
We report the elusive X-ray structure of the Dess-Martin periodinane (DMP), a hypervalent iodine reagent popular amongst synthetic chemists. In the solid state, the highly crystalline compound forms an intricate coordination polymer held together by intermolecular halogen and hydrogen bonds.