159950-96-6 Usage
Explanation
The molecular formula represents the number of atoms of each element present in a molecule of the compound.
Explanation
The compound's structure consists of a benziodoxole ring, which is a fused ring system containing oxygen and iodine, and a sulfone group, which is a sulfur atom bonded to two oxygen atoms.
3. Synthetic organic compound
Explanation
It is a chemical compound that is artificially synthesized, as opposed to being naturally occurring.
4. Used as a reagent in organic synthesis
Explanation
The compound is utilized as a reagent, which is a substance that initiates or accelerates a chemical reaction without being consumed in the process.
Explanation
The compound is particularly effective in converting alcohols (R-OH) into carbonyl compounds (R-C=O), which is an important transformation in organic chemistry.
6. Mild and selective oxidizing properties
Explanation
The compound is known for its ability to selectively oxidize certain functional groups without affecting others, making it a valuable tool in organic synthesis.
7. Development of new synthetic routes and modification of natural products
Explanation
Due to its selective oxidizing properties, the compound can be used to develop new synthetic routes and modify natural products, which can lead to the discovery of new compounds with potential applications.
Explanation
The compound has been studied for its potential use in treating diseases such as cancer, although further research is needed to fully understand its therapeutic potential.
Explanation
As with all chemicals, it is important to follow safety guidelines and take necessary precautions when handling 1-[[(4-METHYLPHENYL)SULPHONYL]OXY]-1,2-BENZIODOXOL-3(1H)-ONE to prevent any harmful consequences.
Chemical structure
Contains a benziodoxole ring and a sulfone group
Specific application
Oxidation of alcohols to carbonyl compounds
Potential therapeutic applications
Treatment of various diseases, including cancer
Safety measures
Appropriate precautions should be taken when handling
Check Digit Verification of cas no
The CAS Registry Mumber 159950-96-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,9,9,5 and 0 respectively; the second part has 2 digits, 9 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 159950-96:
(8*1)+(7*5)+(6*9)+(5*9)+(4*5)+(3*0)+(2*9)+(1*6)=186
186 % 10 = 6
So 159950-96-6 is a valid CAS Registry Number.
InChI:InChI=1/C14H11IO5S/c1-10-6-8-11(9-7-10)21(17,18)20-15-13-5-3-2-4-12(13)14(16)19-15/h2-9H,1H3
159950-96-6Relevant articles and documents
Preparation and chemistry of 1-organosulfonyloxy-1,2-benziodoxol-3-(1H)-ones: First example of a stable adduct of 2-iodosobenzoic acid with strong acid
Zhdankin, Viktor V.,Kuehl, Chris J.,Bolz, Jason T.,Formaneck, Mark S.,Simonsen, Angela J.
, p. 7323 - 7326 (1994)
1-Organosulfonyloxy-1,2-benziodoxol-3-(1H)-ones (3, 4, 5) can be present in one step from 2-iodosobenzoic acid and the corresponding sulfonic acids or Me3SiOTf. Reactions of these compounds with bis(trimethylsilyl)acetylene or cyanotrimethylsil
Tosyloxybenziodoxolone: A Platform for Performing the Umpolung of Alkynes in One-Pot Transformations
Borrel, Julien,Waser, Jerome
supporting information, p. 142 - 146 (2021/12/27)
Ethynylbenziodoxolones (EBXs) are commonly encountered reagents for the electrophilic alkynylation of nucleophiles. Herein, we report a one-pot, two-step process for EBX generation and their direct application in substrate functionalization. Our approach enables us to bypass the originally mandatory isolation and purification of the reagents, resulting in a more efficient synthesis. We could apply this process to seven different transformations involving both two- and one-electron nucleophiles to obtain a large variety of alkynylated products.
Pd(II) catalyzed ortho C-H iodination of phenylcarbamates at room temperature using cyclic hypervalent iodine reagents
Sun, Xiuyun,Yao, Xia,Zhang, Chao,Rao, Yu
, p. 10014 - 10017 (2015/06/22)
A novel approach to access ortho iodinated phenols using cyclic hypervalent iodine reagents through palladium(II) catalyzed C-H activation has been developed through weak coordination. The reaction showed excellent regioselectivity, reactivity and good functional group tolerance. A unique mechanism was proposed.
Solvent-free reactions with hypervalent iodine reagents
Yusubov, Mekhman S.,Wirth, Thomas
, p. 519 - 521 (2007/10/03)
(Chemical Equation Presented) We describe solvent-free reactions for the synthesis of hypervalent iodine reagents and their use in solid-state reactions. Improved yields and higher purities of the products are observed.
