7367-84-2Relevant articles and documents
Transforming Olefins into γ,δ-Unsaturated Nitriles through Copper Catalysis
Wu, Xuesong,Riedel, Jan,Dong, Vy M.
supporting information, p. 11589 - 11593 (2017/09/11)
We have developed a strategy to transform olefins into homoallylic nitriles through a mechanism that combines copper catalysis with alkyl nitrile radicals. The radicals are easily generated from alkyl nitriles in the presence of the mild oxidant di-tert-butyl peroxide. This cross-dehydrogenative coupling between simple olefins and alkylnitriles bears advantages over the conventional use of halides and toxic cyanide reagents. With this method, we showcase the facile synthesis of a flavoring agent, a natural product, and a polymer precursor from simple olefins.
Pheromones, XXXII. - Synthons for the preparation of bisolefinic lepidoptera pheromones
Bestmann,Koschatzky,Schaetzke,et al.
, p. 1705 - 1720 (2007/10/02)
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