80225-50-9

Basic information

• Product Name: Benzene, [(S)-(1-methylethyl)sulfinyl]-
• CAS NO: 80225-50-9
• Molecular Formula: C9H12OS
• Molecular Weight: 168.26
• Mol File: 80225-50-9.mol
• Article Data: 41

Chemical Properties

• CAS DataBase Reference: Benzene, [(S)-(1-methylethyl)sulfinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(S)-(1-methylethyl)sulfinyl]-(80225-50-9)
• EPA Substance Registry System: Benzene, [(S)-(1-methylethyl)sulfinyl]-(80225-50-9)

Safety Data

• Hazardous Substances Data: 80225-50-9(Hazardous Substances Data)

Upstream product

• 3019-20-3 isopropylthiobenzene 
• 4170-69-8 isopropyl phenyl sulfoxide 
• 499140-12-4 benzyl (2R,4S,5R)-4-methyl-5-phenyl-1,2,3-oxathiazolidine-2-oxide-3-carboxilate 
• 108-86-1 bromobenzene 
• 143505-46-8 2-propyl 2-(trimethylsilyl)ethyl sulfoxide 
• 670-98-4 methyl benzenesulfinate 
• 138689-92-6 phenyl isopropenyl sulfoxide 
• 945-51-7 1,1'-sulfinylbisbenzene 
• 3536-97-8 diisopropylmagnesium 
• 939962-74-0 bis(2,2’-bromophenyl) sulfoxide 
• 137956-98-0 Propane-2-sulfinic acid (R)-((1S,2R)-2-hydroxy-1-methyl-2-phenyl-ethyl)-methyl-amide 
• 911820-11-6 3-(isopropylsulfinyl)propionic acid tert-butyl ester 
• 591-50-4 iodobenzene 
• 583-53-9 2,3-dibromobenzene 

Relevant articles and documents

Exploiting Substrate Diversity for Preparing Synthetically Valuable Sulfoxides via Asymmetric Hydrogenative Kinetic Resolution

A detailed study is disclosed on the Rh-mediated hydrogenative kinetic resolution of α,β-unsaturated sulfoxides with alkyl and aryl substituents at the α-, E- and Z-positions of the double bond. This stereoselective catalytic methodology has enabled the p

Palladium/PC-Phos-Catalyzed Enantioselective Arylation of General Sulfenate Anions: Scope and Synthetic Applications

Herein we reported an efficient palladium-catalyzed enantioselective arylation of both alkyl and aryl sulfenate anions to deliver various chiral sulfoxides in good yields (up to 98%) with excellent enantioselectivities (up to 99% ee) by the use of our developed chiral O,P-ligands (PC-Phos). PC-Phos are easily prepared in short steps from inexpensive commercially available starting materials. The single-crystal structure of the PC4/PdCl2 showed that a rarely observed 11-membered ring was formed via the O,P-coordination with the palladium(II) center. The salient features of this method include general substrate scope, ease of scale-up, applicable to the late-stage modification of bioactive compounds, and the synthesis of a marketed medicine Sulindac.

Method for catalyzing asymmetric oxidation of sulfur ether

The invention provides a method for asymmetrically oxidizing sulfur ether. The sulfur ether is subjected to asymmetric catalytic oxidation reaction by taking a chiral complex formed by a four-tooth nitrogen organic ligand and a metal scandium compound as a catalyst and taking hydrogen peroxide as an oxidizing agent to obtain a corresponding chiral sulfoxide compound, and the yield and the enantioselectivity are more than 90 percent. The reaction has the advantages of cleanness, mild reaction condition, high conversion rate and high enantioselectivity. The method has an industrial prospect.