138689-92-6

Basic information

• Product Name: Benzene, [(1-methylethenyl)sulfinyl]-
• CAS NO: 138689-92-6
• Molecular Formula: C9H10OS
• Molecular Weight: 166.244
• Mol File: 138689-92-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, [(1-methylethenyl)sulfinyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1-methylethenyl)sulfinyl]-(138689-92-6)
• EPA Substance Registry System: Benzene, [(1-methylethenyl)sulfinyl]-(138689-92-6)

Safety Data

• Hazardous Substances Data: 138689-92-6(Hazardous Substances Data)

Upstream product

• 1859-03-6 ethyl benzenesulfinate 
• 13291-18-4 isopropenylmagnesium bromide 
• 74338-92-4 3-bromo-2-phenylsulphinylyprop-1-ene 
• 7594-43-6 isopropenyl phenyl sulfide 

Downstream Products

• 76380-14-8 phenyl 2-propenyl sulfone 
• 138689-93-7 5-Benzenesulfinyl-5-methyl-bicyclo[2.2.1]hept-2-ene 
• 4170-69-8 (R)-(isopropylsulfinyl)benzene 
• 80225-50-9 (S)-isopropyl phenyl sulfoxide 
• 69333-65-9 (1-Ethoxy-propane-2-sulfonyl)-benzene 
• 29290-73-1 C₁₅H₁₆O₂S₂ 

Relevant articles and documents

Reactions of Vinyl Sulfoxides with Magnesium Amides. One-Pot Synthesis of Symmetrical and Unsymmetrical β-(Dialkylamino) Dithioacetals

Vinyl sulfoxides (PhSOCR1=CHR2: R1 = H, Me, or Ph; R2 = H or Me) were treated with (dialkylamino)magnesium reagents, generated in situ from the reaction of EtMgBr with secondary amines (R3R4NH: R3 = Et, i-Pr, or Bn; R4 = Me, Et, or i-Pr) in refluxing Et2O for 1 h, and stirring at room-temperature overnight gave the corresponding symmetrical β-(dialkylamino) dithioacetals [(PhS)2CR1CHR2NR3R4] in 24-84% yields. When the (diethylamino)magnesium reagent was treated with appropriate thiols (RSH; R = p-ClC6H4 or Bn) prior to the interaction with phenyl vinyl sulfoxide, the corresponding unsymmetrical β-(diethylamino) dithioacetals [(PhS)(RS)CHCH2NEt2] were produced in 63-67% yields.