51351-89-4Relevant articles and documents
A simple synthesis of some new arylsulfonylnitromethanes
Aleksiev,Ivanova,Valeva
experimental part, p. 743 - 747 (2012/06/18)
Arylsulfonylnitromethanes were obtained by a nucleophilic substitution reaction. The suggested method of obtaining arylsulfonylnitromethanes has some important advantages over the methods known so far: It is a relatively short, one-stage process; no byproducts are obtained, so there is no need for further procedures to separate the main products from thereaction mixture; and the final compounds possess a good degree of purity. The structure of the new products were confirmed by 1H NMR, IR, and elemental analysis. The solid state structure of 6 was established by X-ray analysis. Copyright
Pathways in the Reactions of Nitronate Ions with Sulphonyl Halides
Pigou, Paul E.,Stirling, Charles J. M.
, p. 725 - 730 (2007/10/02)
Primary and tertiary nitronate ions and sulphonyl bromides and iodides rapidly equilibrate with the nitrohalides and sulphinate ion.Products are determined by solvent and by the occurence of cross-equilibrum reactions, some of which have single-electron-transfer mechanism.The reaction of arene-sulphinate and thiolate ions with 1,2-dibromo-2-nitro-1-phenylethane gave E-β-nitrostyrene by Z-philic elimination in both cases, but the more basic thiolate ion also gave, by protophilic elimination, 2-bromo-2-nitro-1-phenylethene.
Silyl Nitronates in Organic Synthesis. Routes to Heterocycles and Cyclopentanoids. Synthesis of Allethrolone and Calythrone. Acylation and Cyanohydroxylation of Double Bonds. An Exploratory Study
Andersen, Soeren H.,Das, Nalin B.,Joergensen, Ruth D.,Kjeldsen, Gunhild,Knudsen, Jes S.,et al.
, p. 1 - 14 (2007/10/02)
Silyl nitronates are versatile reagents for the preparation of heterocycles by dipolar addition to double bonds.The intermediate isoxazolidines can be transformed to 2-isoxazolines, isoxazoles, furans, dihydrofuranones, pyrazoles, pyridazines and pyridazones.Reduction of 2-isoxazolines with Ti3+ leads to hydroxylated 1,4-diketones, which subsequently can be cyclized to cyclopentenones.Routes to calythrone, rethrolones, prostanoids and a number of naturally occurring dihydrofuranones are devised, as well as synthetic procedures for acylation, preparation of endiones, hydroxyacylation, cyanation and hydroxycyanation of double bonds.