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1950-69-2

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1950-69-2 Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 28, p. 2766, 1963 DOI: 10.1021/jo01045a066

Check Digit Verification of cas no

The CAS Registry Mumber 1950-69-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,9,5 and 0 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 1950-69:
(6*1)+(5*9)+(4*5)+(3*0)+(2*6)+(1*9)=92
92 % 10 = 2
So 1950-69-2 is a valid CAS Registry Number.
InChI:InChI=1/C7H7BrO2S/c1-6-2-4-7(5-3-6)11(8,9)10/h2-5H,1H3

1950-69-2Relevant articles and documents

Solid-phase intermolecular radical reactions 1. Sulfonyl radical addition to isolated alkenes and alkynes

Caddick, Stephen,Hamza, Daniel,Wadman, Sjoerd N.

, p. 7285 - 7288 (1999)

The addition of toluenesulfonyl radicals to solid-supported alkenes and alkynes gives bromo-sulfonyl alkenes and alkanes in good yields.

Facile synthesis of sulfonyl chlorides/bromides from sulfonyl hydrazides

Chen, Rongxiang,Xu, Shaohong,Shen, Fumin,Xu, Canran,Wang, Kaikai,Wang, Zhanyong,Liu, Lantao

, (2021/09/20)

A simple and rapid method for efficient synthesis of sulfonyl chlorides/bromides from sulfonyl hydrazide with NXS (X = Cl or Br) and late-stage conversion to several other functional groups was described. A variety of nucleophiles could be engaged in this transformation, thus permitting the synthesis of complex sulfonamides and sulfonates. In most cases, these reactions are highly selective, simple, and clean, affording products at excellent yields.

Norbornadiene-bridged diarylethenes and their conversion into turn-off fluorescent photoswitches

Büllmann, Simon M.,J?schke, Andres

supporting information, p. 7124 - 7127 (2020/07/14)

We describe the synthesis and characterization of novel diarylethene photoswitches that contain a norbornadiene bridge and operate as p-type positive photochromes. One of the double bonds of norbornadiene is furthermore utilized to attach a fluoresceine tetrazine by an iEDDA cascade reaction, thereby forming a turn-off mode fluorescent photoswitch. This journal is

Electrochemically induced oxidative S-O coupling: synthesis of sulfonates from sulfonyl hydrazides and N-hydroxyimides or N-hydroxybenzotriazoles

Terent'ev, Alexander O.,Mulina, Olga M.,Parshin, Vadim D.,Kokorekin, Vladimir A.,Nikishin, Gennady I.

supporting information, p. 3482 - 3488 (2019/04/14)

The process of oxidative S-O coupling under the action of electric current was developed. Aryl, hetaryl and alkyl sulfonyl hydrazides and N-hydroxy compounds (N-hydroxyimides and N-hydroxybenzotriazoles) are applied as starting reagents for the preparation of sulfonates. The reaction is carried out under constant current conditions in an experimentally convenient undivided electrochemical cell equipped with a graphite anode and a stainless steel cathode under a high current density (60 mA cm?2). NH4Br in this process acts as a supporting electrolyte and participates in the oxidation of the starting compounds to form a coupling product. The developed strategy represents a quite atom-efficient approach: one partner loses two nitrogen and three hydrogen atoms, while another one loses only one hydrogen atom. Cyclic voltammetry and the control experiment allowed us to propose possible reaction pathways: generated through anodic oxidation molecular bromine or its higher oxidation state derivatives oxidize the starting compounds to form reactive species, which couple to form the S-O bond.

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