4255-62-3Relevant articles and documents
THE MECHANISM OF PHOTOREDUCTION OF CYCLOHEXENONES TO CYCLOHEXANONES IN ISOPROPYL ALCOHOL
Schuster, David I.,Nunez, Ivan M.,Chan, Chung B.
, p. 1187 - 1190 (1981)
The photoreduction of cyclohexenones in 2-propanol is initiated by H-abstraction at Cβ of the enone 3?,?* state, as shown by the reaction course in deuterated solvents.
Iron-catalyzed oxidative functionalization of C(sp3)-H bonds under bromide-synergized mild conditions
Yu, Han,Zhao, Qixin,Wei, Zheyu,Wu, Zhikang,Li, Qi,Han, Sheng,Wei, Yongge
supporting information, p. 7840 - 7843 (2019/07/12)
An efficient oxidation and functionalization of C-H bonds with an inorganic-ligand supported iron catalyst and hydrogen peroxide to prepare the corresponding ketones was achieved using the bromide ion as a promoter. Preliminary mechanistic investigations indicated that the bromide ion can bind to FeMo6 to form a supramolecular species (FeMo6·2Br), which can effectively catalyze the reaction.
Catalyst-controlled aliphatic C—H oxidations
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Page/Page column 36-37; 47-48, (2018/04/20)
The invention provides simple small molecule, non-heme iron catalyst systems with broad substrate scope that can predictably enhance or overturn a substrate's inherent reactivity preference for sp3-hybridized C—H bond oxidation. The invention also provides methods for selective aliphatic C—H bond oxidation. Furthermore, a structure-based catalyst reactivity model is disclosed that quantitatively correlates the innate physical properties of the substrate to the site-selectivities observed as a function of the catalyst. The catalyst systems can be used in combination with oxidants such as hydrogen peroxide to effect highly selective oxidations of unactivated sp3 C—H bonds over a broad range of substrates.