35216-79-6

Basic information

• Product Name: [1,1'-Binaphthalen]-2-ol, (1R)-
• CAS NO: 35216-79-6
• Molecular Formula: C20H14O
• Molecular Weight: 270.331
• Mol File: 35216-79-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: [1,1'-Binaphthalen]-2-ol, (1R)-(CAS DataBase Reference)
• NIST Chemistry Reference: [1,1'-Binaphthalen]-2-ol, (1R)-(35216-79-6)
• EPA Substance Registry System: [1,1'-Binaphthalen]-2-ol, (1R)-(35216-79-6)

Safety Data

• Hazardous Substances Data: 35216-79-6(Hazardous Substances Data)

Upstream product

• 90-14-2 1-Iodonaphthalene 
• 15147-55-4 2-naphtholate 
• 135-19-3 β-naphthol 
• 881209-92-3 (R)-2′-hydroxy-[1,1′-binaphthalen]-2-yl trifluoromethanesulfonate 
• 212832-66-1 4-(t-butyldiphenylsilyl)phenylmagnesium bromide 
• 573-97-7 1-bromo-2-naphthol 
• 13922-41-3 1-Naphthylboronic acid 
• 35216-79-6 1-naphthyl-2-naphthol 
• 93-97-0 benzoic acid anhydride 

Downstream Products

• 103277-81-2 (aR)-1,1'-binaphthyl-2-yl benzoylformate 
• 132532-07-1 [1,1'-binaphthalen]-2-yldiphenylphosphine oxide 
• 264188-44-5 (S)-2-diphenylphosphino-1,1'-binaphthyl 
• 124730-01-4 2-Hydroxy-2-phenyl-propionic acid [1,1']binaphthalenyl-2-yl ester 
• 74866-28-7 2,2'-dibromo-1,1'-binaphthyl 

Relevant articles and documents

Fluxionally chiral DMAP catalysts: Kinetic resolution of axially chiral biaryl compounds

Can organocatalysts that incorporate fluxional groups provide enhanced selectivity in asymmetric transformations? To address this issue, we have designed chiral 4-dimethylaminopyridine (DMAP) catalysts with fluxional chirality. These catalysts were found

Highly enantioselective benzylic hydroxylation with concave type of (salen)manganese(III) complex

Newly-designed optically active (salen)manganese(III) complexes (5) catalyze highly enantioselective benzylic hydroxylation and moderate level of enantiomer-differentiating oxidation (kinetic resolution) of the resulting benzylic alcohols. Thus, the enantiomeric excess of hydroxylation product was increased through kinetic resolution, as the reaction time was prolonged. For example, enantiomeric excess of 3,3-dimethylindan-1-ol, the hydroxylation product of 1,1-dimethylindan using 5a as a catalyst in chlorobenzene, was 84% alter 10 min and 90% after 20 h.

PHOTOSTIMULATED REACTION OF ARYL IODIDES WITH 2-NAPHTHOXIDE IONS BY THE SRN1 MECHANISM

The photostimulated reactions of p-iodoanisole (2) and 1-iodonaphthalene (7) with 2-naphthoxide ions in liquid ammonia gave the corresponding 1-aryl-2-naphthols as the only substitution product.These reactions are proposed to proceed via the SRN1 mechanism for nucleophilic aromatic substitution.