350587-04-1Relevant articles and documents
Modulating photoswitch performance with halogen, coordinative and hydrogen bonding: A comparison of relative bond strengths
Berryman, Orion B.,Erdélyi, Máté,Lindblad, Sofia,Sethio, Daniel
, p. 6261 - 6263 (2021)
The behavior of an enediyne photoswitch is modulated with halogen bonding, coordinative bonding and hydrogen bonding. Through NMR and computational studies we demonstrate that the relative strength of the secondary bonding directly influences the rate of photoisomerization and the photostationary state.
Aerobic Cu-catalyzed oxidative 1?:?2 coupling of benzynes with terminal alkynes
Lu, Tianhao,Shen, Yong,Wang, Min,Zhang, Zibing,Li, Shijun,Xie, Chunsong
supporting information, p. 8214 - 8217 (2020/08/17)
Cu-Catalyzed oxidative 1?:?2 couplings of arynes with nucleophilic terminal alkynes under aerobic conditions are described herein. A mechanistic investigation revealed a plausible involvement of an aryl-Cu(iii)-generating pathway. By this method, ubiquitous arenediynes can be efficiently assembled in a single step under mild conditions. This journal is
Palladium-catalyzed oxidative homocoupling reaction of terminal acetylenes using trans-bidentatable 1-(2-pyridylethynyl)-2-(2-thienylethynyl)benzene
Atobe, Shingo,Sonoda, Motohiro,Suzuki, Yuki,Yamamoto, Takuya,Masuno, Haruna,Shinohara, Hiroyuki,Ogawa, Akiya
, p. 359 - 370 (2013/03/28)
Palladium-catalyzed oxidative homocoupling of terminal acetylenes, in air, occurred in the presence of 1-(2-pyridylethynyl)-2-(2-thienylethynyl)benzene as ligand, affording the corresponding conjugated diynes.