239110-15-7

Basic information

• Product Name: Fluopicolide
• Synonyms: infinito;2,6-Dichloro-N-[[3-chloro-5-(trifluoro-methyl)-2-pyridinyl]methyl]benzamide;Fluopicolide;2,6-Dichloro-N-[3-chloro-5-(trifluoromethyl)-2-pyridylmethyl]benzamide;Fluopicolide [iso];2,6-Dichloro-N-((3-chloro-5-(trifluoroMethyl)pyridin-2-yl)Methyl)benzaMide;BenzaMide,2,6-dichloro-N-[[3-chloro-5-(trifluoroMethyl)-2-pyridinyl]Methyl]-;Fluopicolide 0
• CAS NO: 239110-15-7
• Molecular Formula: C₁₄H₈Cl₃F₃N₂O
• Molecular Weight: 383.58
• EINECS: 259-565-9
• Mol File: 239110-15-7.mol
• Article Data: 3

Chemical Properties

• Melting Point: 150 °C
• Boiling Point: 432.1 °C at 760 mmHg
• Flash Point: 215.1 °C
• Appearance: /
• Density: 1.515 g/cm³
• Vapor Pressure: 1.14E-07mmHg at 25°C
• Refractive Index: 1.562
• PKA: 11.14±0.46(Predicted)
• CAS DataBase Reference: Fluopicolide(CAS DataBase Reference)
• NIST Chemistry Reference: Fluopicolide(239110-15-7)
• EPA Substance Registry System: Fluopicolide(239110-15-7)

Safety Data

• Hazard Codes: N
• Statements: 50/53
• Safety Statements: 60-61
• RIDADR: UN3077 9/PG 3
• Hazardous Substances Data: 239110-15-7(Hazardous Substances Data)

Usage

Definition

ChEBI: A member of the class of benzamides obtained by formal condensation of the carboxy group of 2,6-dichlorobenzoic acid with the amino group of [3-chloro-5-(trifluoromethyl)pyridin-2-yl]methylamine. A fungicide used for the control of a range of diseases incl ding downy mildew and blight.

Agricultural Uses

Fungicide: Fluopicolide is targeted for control of oomycete fungal diseases on turf, ornamentals, and several food uses including grapes and six crop groupings (leafy vegetables, fruiting vegetables, brassica vegetables, root and tuber vegetables, bulb vegetables, and cucurbits) that may be grown throughout the U.S [83] .

Trade name

INFINITO?, Bayer; PRECIDIO

InChI:InChI=1/C14H8Cl3F3N2O/c15-8-2-1-3-9(16)12(8)13(23)22-6-11-10(17)4-7(5-21-11)14(18,19)20/h1-5H,6H2,(H,22,23)

Upstream product

• 4659-45-4 2,6-Dichlorobenzoyl chloride 
• 326476-49-7 [3-chloro-5-(trifluoromethyl)-pyridin-2-yl]methanamine hydrochloride 
• 1194-65-6 2,6-dichloro-benzonitrile 
• 1033463-31-8 (3-chloro-5-(trifluoromethyl)pyridin-2-yl)methanol 

Relevant articles and documents

PROCESS FOR THE PREPARATION OF FLUOPICOLIDE

The present invention relates to an improved process for the preparation of substituted pyridylmethyl- benzamide derivatives of formula (I), in particular 2,6-Dichloro-N-{[3-chloro-5-(trifluoromethyl)-2- pyridyl]methyl}benzamide (Fluopicolide), from subst

CATALYTIC HYDROGENATION OF SUBSTITUTED CYANOPYRIDINES AND PROCESS FOR PREPARING SUBSTITUTED PYRIDYLMETHYLBENZAMIDES

The present invention relates to novel processes for the preparation of substituted pyridyl- methylbenzamide derivatives of formula (I), in particular 2,6-dichloro-N- {[3-chloro-5-(trifluoromethyl)- 2-pyridyl]methyl}benzamide (Fluopicolide), and for the catalytic hydrogenation of substituted cyanopyridine derivatives, in particular 3-chloro-2-cyano-5-trifluoromethylpyridine [= Py-CN] to the corresponding substituted 2-methylaminopyridine derivatives, in particular 2-aminomethyl-3-chloro-5- trifluoromethylpyridine [= Py-methylamine] or salts thereof in the presence of metal catalysts such as in particular palladium catalysts, catalytic modifiers and acids.