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1568-66-7

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1568-66-7 Usage

General Description

1-nitro-4-(prop-2-en-1-yloxy)benzene, also known as 4-nitrophenoxypropene, is an organic compound with the molecular formula C9H9NO3. This chemical structure consists of a benzene ring substituted with a nitro functional group and a prop-2-en-1-yloxy side chain. It belongs to the class of benzenes and is a derivative of nitrobenzene, which is characterized by a benzene ring bearing a nitro group. It is used in various research and industrial processes but has a potential for explosion due to the nitro functional group. Information regarding its hazards and safety measures should be sought from the appropriate Material Safety Data Sheets (MSDS).

Check Digit Verification of cas no

The CAS Registry Mumber 1568-66-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,5,6 and 8 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 1568-66:
(6*1)+(5*5)+(4*6)+(3*8)+(2*6)+(1*6)=97
97 % 10 = 7
So 1568-66-7 is a valid CAS Registry Number.

1568-66-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-nitro-4-prop-2-enoxybenzene

1.2 Other means of identification

Product number -
Other names Ether,allyl p-nitrophenyl

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1568-66-7 SDS

1568-66-7Relevant articles and documents

Improved protocols for molybdenum- und tungsten-catalyzed hydrostannations

Wesquet, Alexander O.,Kazmaier, Uli

, p. 1395 - 1404 (2009)

A series of (isonitrile)tungsten carbonyl complexes of type W(CO) m(CNR)n has been synthesized and evaluated as hydrostannation catalysts. The results are compared with those obtained by the previously reported tri(tert-butylisonitri

Palladium-Catalyzed Double-Decarboxylative Addition to Pyrones: Synthesis of Conjugated Dienoic Esters

Maji, Tapan,Tunge, Jon A.

, p. 4766 - 4769 (2015)

An interceptive decarboxylative allylation protocol has been developed utilizing pyrone as a C4 synthon. This palladium-catalyzed transformation difunctionalizes the pyrone moiety by in situ generation and activation of both the electrophile and nucleophi

Pyrene-Tagged Alcoholic Ionic Liquids as Phase Transfer Catalysts for Nucleophilic Fluorination

Taher, Abu,Kim, Dong Wook

, p. 1140 - 1146 (2020)

Functional group?activity relationships of pyrene-tagged ionic liquid (PTIL)-based organocatalysts for nucleophilic fluorination using alkali metal fluorides (MFs) are described, which demonstrate that the pyrene, oligoether and alcohol moieties on the imidazolium ring are vital for efficient catalysis. Further investigation of these findings led to the discovery of new strategy, which showed superior catalyst separation process, i.e., catalyst is effortlessly separated from the reaction mixture using reduced graphene oxide. The catalytic efficiency of the PTIL as a phase transfer catalyst was demonstrated by the high conversion of the reactants up to 98% fluorinated yield using MFs in CH3CN or t-amyl alcohol. Importantly, the catalyst not only enhanced the reactivity of bimolecular nucleophilic substitutions (SN2) within a short reaction time and reduces the formation of by-products but also affords high yield with easy isolation and separation under mild conditions.

Aluminium chloride-potassium iodide-acetonitrile system: A mild reagent system for aromatic claisen rearrangement at ambient temperature

Bhattacharyya, Nayan Kamal,Dutta, Deepjyoti,Biswas, Joydeep

, (2021/06/28)

Claisen rearrangement is used as the standard methods for the generation of complex organic substance. It is one of the well-known methods for the introduction of carbon-carbon bond. We have developed a protocol using allyl aryl ether as a substrate and AlCl3-KI as a mild reagent system and acetonitrile (CH3CN) is taken as solvent at ambient temperature. The reagent system presented in this current work is found to be appropriate for Claisen rearrangement of several aromatic alcohols with excellent yields.

Aryl Ether Syntheses via Aromatic Substitution Proceeding under Mild Conditions

Ando, Shin,Tsuzaki, Marina,Ishizuka, Tadao

, p. 11181 - 11189 (2020/10/12)

In this study, mild conditions for aromatic substitutions during the syntheses of aryl ethers were developed. In the reaction conditions, the choices of solvent, base, and the sequence for the addition of the reagents proved important. A wide variety of alcohols were used directly as nucleophiles and smoothly reacted with aryl chlorides that possessed either a nitro or a cyano group at either the ortho- or para-position. Controlled experiments we performed suggested that the reaction underwent a charge-transfer process mediated by a combination of DMF and tert-BuOK.

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