35466-83-2 Usage
Description
Allyl methyl carbonate is a chemical compound that is used as an intermediate in the synthesis of various organic compounds. It is a colorless liquid with a characteristic odor and is soluble in water.
Uses
Used in the Chemical Industry:
Allyl methyl carbonate is used as an intermediate in the Pd(0)-mediated synthesis of allyl aryl ethers and sulfides, and α,β-unsaturated carbonyls. This application is important for the production of various organic compounds that have a wide range of uses in different industries.
Used in the Pharmaceutical Industry:
Allyl methyl carbonate is used as a building block in the synthesis of pharmaceutical compounds. Its reactivity and versatility make it a valuable component in the development of new drugs and drug candidates.
Used in the Agrochemical Industry:
Allyl methyl carbonate is used in the synthesis of agrochemicals, such as pesticides and herbicides. Its ability to form stable intermediates makes it a useful component in the development of effective and safe agrochemical products.
Used in the Flavor and Fragrance Industry:
Allyl methyl carbonate is used as a starting material in the synthesis of various flavor and fragrance compounds. Its unique chemical properties allow for the creation of a wide range of scents and flavors that are used in the production of perfumes, cosmetics, and food products.
Overall, allyl methyl carbonate is a versatile and valuable chemical compound with a wide range of applications in various industries. Its unique properties and reactivity make it an essential component in the synthesis of many organic compounds, contributing to the development of new products and technologies.
Check Digit Verification of cas no
The CAS Registry Mumber 35466-83-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,5,4,6 and 6 respectively; the second part has 2 digits, 8 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 35466-83:
(7*3)+(6*5)+(5*4)+(4*6)+(3*6)+(2*8)+(1*3)=132
132 % 10 = 2
So 35466-83-2 is a valid CAS Registry Number.
InChI:InChI=1/C5H8O3/c1-3-4-8-5(6)7-2/h3H,1,4H2,2H3
35466-83-2Relevant articles and documents
Synthesis of Carbonate Esters by Carboxymethylation Using NaAlO2 as a Highly Active Heterogeneous Catalyst
Ramesh, Sreerangappa,Indukuri, Kiran,Riant, Olivier,Debecker, Damien P.
, p. 1846 - 1851 (2019/01/04)
Sodium aluminate is presented as a highly active heterogeneous catalyst that is able to convert a range of alcohols into the corresponding unsymmetrical carbonate esters by reaction with dimethyl carbonate. Preparing NaAlO2 via spray drying boosts the basic properties and the activity of the catalyst.
Rate and product studies on the solvolyses of allyl chloroformate
Koh, Han Joong,Kang, Suk Jin
, p. 4117 - 4121 (2013/08/23)
The solvolysis rate constants of allyl chloroformate (CH 2=CHCH2OCOCl, 3) in 30 different solvents are well correlated with the extended Grunwald-Winstein equation, using the NT solvent nucleophilicity scale and YCl solvent ionizing scale, with the sensitivity values of 0.93 ± 0.05 and 0.41 ± 0.02 for l and m, respectively. These l and m values can be considered to support a S N2 reaction pathway. The activation enthalpies (ΔH≠) were 12.5 to 13.4 kcal·mol-1 and the activation entropies (ΔS≠) were -34.4 to -37.3 cal·mol-1·K -1, which is also consistent with the proposed bimolecular reaction mechanism. The solvent kinetic isotope effect (SKIE, kMeOH/k MeOD) of 2.16 was also in accord with the SN2 mechanism. The values of product selectivity (S) for the solvolyses of 3 in alcohol/water mixtures was 1.3 to 3.9, which is also consistent with the proposed bimolecular reaction mechanism.
ETHYLENICALLY UNSATURATED MONOMERS COMPRISING ALIPHATIC AND AROMATIC MOIETIES
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Page/Page column 35-38, (2009/10/22)
Polymerizable monomers comprising at least one 1- or 2-propylene moiety and further comprising both aromatic moieties and additional aliphatic moieties and polymerizable mixtures, resins and thermoset products based on these monomers.