1520814-76-9

Basic information

• Product Name: 2-iodophenyl 2-naphthyl sulfide
• Synonyms: 2-iodophenyl 2-naphthyl sulfide
• CAS NO: 1520814-76-9
• Molecular Weight: 362.234
• Mol File: 1520814-76-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-iodophenyl 2-naphthyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-iodophenyl 2-naphthyl sulfide(1520814-76-9)
• EPA Substance Registry System: 2-iodophenyl 2-naphthyl sulfide(1520814-76-9)

Safety Data

• Hazardous Substances Data: 1520814-76-9(Hazardous Substances Data)

Upstream product

• 615-42-9 1,2-Diiodobenzene 
• 91-60-1 2-Naphthalenethiol 

Downstream Products

• 205-43-6 Benzo[b]naphtho[1,2-d]thiophene 

Relevant articles and documents

Reaction method of thiophenol and O-diiodobenzene

The invention discloses a reaction method of thiophenol and o-diiodobenzene. The method comprises the following steps: taking thiophenol and o-diiodobenzene as substrates, reacting in a solvent in the presence of a metal hydride, and completing the reaction of thiophenol and o-diiodobenzene to obtain o-iodobenzene sulfide. Under the action of NaH, o-diiodobenzene and thiophenol are subjected to a nucleophilic reaction to generate an o-iodobenzene sulfide product. According to the method, C-S bond coupling is completed without transition metal participation, operation is easy and convenient, and the problems of metal reagent residues, pollution and the like are solved; meanwhile, compared with an existing precursor, o-diiodobenzene is low in price and convenient to prepare, and has better atom economy; and an iodine exists at the ortho-position of the generated product phenyl sulfide, other conversions can be conveniently carried out to obtain various 1, 2-substituted benzene, and particularly, the excellent yield can be obtained by only needing 3 equivalents of metal hydride.

Copper-catalyzed selective single arylsulfanylation of aryl diiodides with aryl thiols

Selective single arylsulfanylation reactions of aryl diiodides with aryl or hetaryl thiols to give a broad array of iodine-functionalized sulfides were developed. Further elaboration of the iodine-containing products to provide a variety of aryl and hetaryl sulfides through coupling reactions was also demonstrated. Georg Thieme Verlag Stuttgart, New York.