1425924-22-6

Basic information

• Product Name: [3-(iodomethyl)phenoxy]triisopropylsilane
• Synonyms: [3-(iodomethyl)phenoxy]triisopropylsilane
• CAS NO: 1425924-22-6
• Molecular Weight: 390.38
• Mol File: 1425924-22-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [3-(iodomethyl)phenoxy]triisopropylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: [3-(iodomethyl)phenoxy]triisopropylsilane(1425924-22-6)
• EPA Substance Registry System: [3-(iodomethyl)phenoxy]triisopropylsilane(1425924-22-6)

Safety Data

• Hazardous Substances Data: 1425924-22-6(Hazardous Substances Data)

Upstream product

• 100-83-4 meta-hydroxybenzaldehyde 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 
• 817166-73-7 3-[(triisopropylsilyl)oxy]benzaldehyde 
• 925417-01-2 3-{[tris(1-methylethyl)silyl]oxy}benzenemethanol 

Downstream Products

• 1425924-23-7 tert-butyl (S)-2-(diphenylmethyleneamino)-3-[3-(triisopropylsilyloxy)phenyl]propanoate 
• 1425924-24-8 tert-butyl (S)-2-(diphenylmethyleneamino)-3-(3-hydroxyphenyl)propanoate 
• 1425924-25-9 tert-butyl (S)-2-amino-3-[3-(triisopropylsilyloxy)phenyl]propanoate 
• 1425924-26-0 tert-butyl (S)-{2-[(S)-2-(tert-butoxycarbonylamino)-3-(methyl)butanamido]-3-[3-(triisopropylsilyloxy)phenyl]}propanoate 
• 1425924-27-1 tert-butyl (S)-{2-[(S)-2-(benzyloxycarbonylamino)-3-(methyl)butanamido]-3-[3-(triisopropylsilyloxy)phenyl]}propanoate 
• 1425924-28-2 (S)-{2-[(S)-2-(benzyloxycarbonylamino)-3-(methyl)butanamido]-3-[3-(triisopropylsilyloxy)phenyl]}propanoic acid 
• 1425924-29-3 methyl (S)-1-{(S)-2-[(S)-2-(benzyloxycarbonylamino)-3-(methyl)butanamido]-3-[3-(triisopropylsilyloxy)phenyl]propanoyl}hexahydropyridazine-3-carboxylate 
• 1425924-30-6 methyl (S)-1-{(S)-2-[(S)-2-amino-3-(methyl)butanamido]-3-[3-(triisopropylsilyloxy)phenyl]propanoyl}hexahydropyridazine-3-carboxylate 

Relevant articles and documents

Synthesis of the tripeptide domain of sanglifehrins using asymmetric phase-transfer catalysis

The tripeptide (S)-valinyl-(S)-m-hydroxyphenylalanyl-(3S)-piperazate common to immunosuppressant sanglifehrins was synthesized from the constituent amino acid residues in nine steps and 42% overall yield. A key construction was the installation of (S) absolute configuration in m-hydroxyphenylalanine using asymmetric phase-transfer catalysis in the presence of N-(1-naphthyl) cinchonidinium bromide. Cbz-protected (S)-valine was first coupled to the amino group of (S)-m-triisopropylsilyloxyphenylalanine tert-butyl ester, and the resulting dipeptide after ester cleavage was linked to (3S)-methyl piperazate.