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  • 13080-85-8 Structure
  • Basic information

    1. Product Name: 4,4'-Bis(4-aminophenoxy)biphenyl
    2. Synonyms: 4,4'-(1,1'-BIPHENYL-4,4'-DIYLDIOXY)DIANILINE;4,4'-(P-BIPHENYLENEDIOXY)DIANILINE;4,4'-BIS(4-AMINOPHENOXY)BIPHENYL;BAPB;4,4-BIS(4-AMINOPHENOXY)BIPHENYL(44BAPOBP) 98%;4,4'-Bis(4-aminophenoxy)biphenyl;4,4'-(1,1'-Biphenyl-4,4'-diylbisoxy)bisaniline;4,4'-(Biphenyl-4,4'-diylbisoxy)bis(aniline)
    3. CAS NO:13080-85-8
    4. Molecular Formula: C24H20N2O2
    5. Molecular Weight: 368.43
    6. EINECS: 1312995-182-4
    7. Product Categories: Biphenyl & Diphenyl ether;Biphenyls (for High-Performance Polymer Research);Functional Materials;Reagent for High-Performance Polymer Research;fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials
    8. Mol File: 13080-85-8.mol
    9. Article Data: 4
  • Chemical Properties

    1. Melting Point: 197-200 °C(lit.)
    2. Boiling Point: 571.365 °C at 760 mmHg
    3. Flash Point: 321.516 °C
    4. Appearance: /
    5. Density: 1.226 g/cm3
    6. Refractive Index: N/A
    7. Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
    8. Solubility: N/A
    9. PKA: 5.10±0.10(Predicted)
    10. CAS DataBase Reference: 4,4'-Bis(4-aminophenoxy)biphenyl(CAS DataBase Reference)
    11. NIST Chemistry Reference: 4,4'-Bis(4-aminophenoxy)biphenyl(13080-85-8)
    12. EPA Substance Registry System: 4,4'-Bis(4-aminophenoxy)biphenyl(13080-85-8)
  • Safety Data

    1. Hazard Codes: Xi
    2. Statements: 36/37/38
    3. Safety Statements: 26-36
    4. WGK Germany: 3
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 13080-85-8(Hazardous Substances Data)

13080-85-8 Usage

Chemical Properties

White powder

Check Digit Verification of cas no

The CAS Registry Mumber 13080-85-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,0,8 and 0 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 13080-85:
(7*1)+(6*3)+(5*0)+(4*8)+(3*0)+(2*8)+(1*5)=78
78 % 10 = 8
So 13080-85-8 is a valid CAS Registry Number.

13080-85-8 Well-known Company Product Price

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  • TCI America

  • (B1671)  4,4'-Bis(4-aminophenoxy)biphenyl  >98.0%(T)

  • 13080-85-8

  • 5g

  • 380.00CNY

  • Detail
  • TCI America

  • (B1671)  4,4'-Bis(4-aminophenoxy)biphenyl  >98.0%(T)

  • 13080-85-8

  • 25g

  • 990.00CNY

  • Detail
  • Aldrich

  • (476358)  4,4′-(1,1′-Biphenyl-4,4′-diyldioxy)dianiline  97%

  • 13080-85-8

  • 476358-5G

  • 677.43CNY

  • Detail

13080-85-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 4,4'-Bis(4-aminophenoxy)biphenyl

1.2 Other means of identification

Product number -
Other names 4-[4-[4-(4-aminophenoxy)phenyl]phenoxy]aniline

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:13080-85-8 SDS

13080-85-8Synthetic route

4,4'-bis(4-nitrophenoxy)biphenyl
17095-00-0

4,4'-bis(4-nitrophenoxy)biphenyl

4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

Conditions
ConditionsYield
With hydrogen; nickel; triethylamine In ethyl acetate at 20 - 60℃; under 11400.8 Torr; Reagent/catalyst; Inert atmosphere;99%
With hydrogenchloride; tin(ll) chloride In water at 60℃; for 3h;63%
4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

4,4'-bis(4-aminophenoxy)biphenyl-3,3'-disulfonic acid
500295-67-0

4,4'-bis(4-aminophenoxy)biphenyl-3,3'-disulfonic acid

Conditions
ConditionsYield
With sulfuric acid at 50℃;100%
Stage #1: 4,4'-bis(4-aminophenoxy)biphenyl With sulfuric acid at 0℃; Heating;
Stage #2: With fuming sulfuric acid at 0 - 50℃; for 2.5h;
4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

4-hydroxy-benzaldehyde
123-08-0

4-hydroxy-benzaldehyde

C38H28N2O4

C38H28N2O4

Conditions
ConditionsYield
With acetic acid In N,N-dimethyl-formamide at 100 - 110℃; for 2h;93.4%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

N-(4-methoxyphenyl)-4-{4-[4-(4-methoxyanilino)phenoxy]phenyl}phenoxyaniline

N-(4-methoxyphenyl)-4-{4-[4-(4-methoxyanilino)phenoxy]phenyl}phenoxyaniline

Conditions
ConditionsYield
With sodium t-butanolate; Ni(0)*2IPr In 1,4-dioxane at 100℃;93%
4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

C38H26Cl2N2O2

C38H26Cl2N2O2

Conditions
ConditionsYield
With acetic acid In N,N-dimethyl-formamide at 100 - 110℃; for 2h;92.7%
4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

chlorobenzene
108-90-7

chlorobenzene

N-phenyl-4-{4-[4-(4-anilinophenoxy)phenyl]phenoxy}aniline

N-phenyl-4-{4-[4-(4-anilinophenoxy)phenyl]phenoxy}aniline

Conditions
ConditionsYield
With sodium t-butanolate; Ni(0)*2IPr In 1,4-dioxane at 100℃;91%
4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

C38H26N4O6

C38H26N4O6

Conditions
ConditionsYield
With acetic acid In N,N-dimethyl-formamide at 100 - 110℃; for 2h;89.2%
4-(4-nitrophenoxy)benzaldehyde
50961-54-1

4-(4-nitrophenoxy)benzaldehyde

4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

C50H34N4O8

C50H34N4O8

Conditions
ConditionsYield
With acetic acid In N,N-dimethyl-formamide at 100 - 110℃; for 2h;88.3%
4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

4-dimethylamino-benzaldehyde
100-10-7

4-dimethylamino-benzaldehyde

C42H38N4O2

C42H38N4O2

Conditions
ConditionsYield
With acetic acid In N,N-dimethyl-formamide at 100 - 110℃; for 2h;86.9%
4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

4-Diethylaminobenzaldehyde
120-21-8

4-Diethylaminobenzaldehyde

C46H46N4O2

C46H46N4O2

Conditions
ConditionsYield
With acetic acid In N,N-dimethyl-formamide at 100 - 110℃; for 2h;82.7%
4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

phenol
108-95-2

phenol

4,4'-bis(4-hydroxyphenyldiazenyl-4-phenoxy)biphenyl

4,4'-bis(4-hydroxyphenyldiazenyl-4-phenoxy)biphenyl

Conditions
ConditionsYield
Stage #1: 4,4'-bis(4-aminophenoxy)biphenyl With hydrogenchloride; sodium nitrite In water at 5℃;
Stage #2: phenol With sodium carbonate; sodium hydroxide In water at 5℃; for 5h;
72%
2-methylchlorobenzene
95-49-8

2-methylchlorobenzene

4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

N-(4-{4-[4-(4-aminophenoxy)phenyl]phenoxy}phenyl)-2-methylaniline

N-(4-{4-[4-(4-aminophenoxy)phenyl]phenoxy}phenyl)-2-methylaniline

Conditions
ConditionsYield
With sodium t-butanolate; Ni(0)*2IPr In tetrahydrofuran at 65℃; for 4h;68%
4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

benzaldehyde
100-52-7

benzaldehyde

C38H28N2O2

C38H28N2O2

Conditions
ConditionsYield
With acetic acid In N,N-dimethyl-formamide at 100 - 110℃; for 2h;63.7%
diethylenetriaminepentaacetic dianhydride
23911-26-4

diethylenetriaminepentaacetic dianhydride

4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

C38H39N5O10
1364601-70-6

C38H39N5O10

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 20℃; Inert atmosphere;33%
4-(p-nonylphenoxy)benzaldehyde

4-(p-nonylphenoxy)benzaldehyde

4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

C68H72N2O4

C68H72N2O4

Conditions
ConditionsYield
With acetic acid In N,N-dimethyl-formamide at 100 - 110℃; for 2h;30.3%
maleic anhydride
108-31-6

maleic anhydride

4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

C32H20N2O6

C32H20N2O6

Conditions
ConditionsYield
Stage #1: maleic anhydride; 4,4'-bis(4-aminophenoxy)biphenyl In acetone at 25℃; for 0.5h;
Stage #2: With magnesium acetate; acetic anhydride; triethylamine In acetone for 1h; Heating;
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride
2540-99-0

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

1,2-bis(4-aminophenoxy)-4-tert-butylbenzene
210492-48-1

1,2-bis(4-aminophenoxy)-4-tert-butylbenzene

Polymer; Monomer(s): 1,2-bis(4-aminophenoxy)-4-tert-butylbenzene; 3,3\,,4,4\-diphenylsulfonetetracarboxylic dianhydride; 4,4\-bis(4-aminophenoxy)biphenyl

Polymer; Monomer(s): 1,2-bis(4-aminophenoxy)-4-tert-butylbenzene; 3,3\,,4,4\-diphenylsulfonetetracarboxylic dianhydride; 4,4\-bis(4-aminophenoxy)biphenyl

Conditions
ConditionsYield
Stage #1: 3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride; 4,4'-bis(4-aminophenoxy)biphenyl; 1,2-bis(4-aminophenoxy)-4-tert-butylbenzene In N,N-dimethyl acetamide at 20℃; for 1h;
Stage #2: at 120 - 250℃; for 1.16667h;
3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride
2540-99-0

3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride

4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

Polymer; Monomer(s): 3,3\,,4,4\-diphenylsulfonetetracarboxylic dianhydride; 4,4\-bis(4-aminophenoxy)biphenyl

Polymer; Monomer(s): 3,3\,,4,4\-diphenylsulfonetetracarboxylic dianhydride; 4,4\-bis(4-aminophenoxy)biphenyl

Conditions
ConditionsYield
Stage #1: 3,3',4,4'-diphenylsulfonetetracarboxylic acid dianhydride; 4,4'-bis(4-aminophenoxy)biphenyl In N,N-dimethyl acetamide at 20℃; for 1h;
Stage #2: at 120 - 250℃; for 1.16667h;
4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

5-(4-acetoxybenzamido)-isophthaloyl dichloride
250267-73-3

5-(4-acetoxybenzamido)-isophthaloyl dichloride

polymer, Mw=48740, Mn=21600; Monomer(s): 5-(4-acetoxybenzamido)isophthaloyl chloride; 4-{4-[4-(p-aminophenoxy)phenyl]phenoxy}aniline

polymer, Mw=48740, Mn=21600; Monomer(s): 5-(4-acetoxybenzamido)isophthaloyl chloride; 4-{4-[4-(p-aminophenoxy)phenyl]phenoxy}aniline

Conditions
ConditionsYield
With pyridine In 1-methyl-pyrrolidin-2-one
phthalic anhydride
85-44-9

phthalic anhydride

4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

1,3-bis(3,4-dicarboxyphenoxy)benzene
18959-91-6

1,3-bis(3,4-dicarboxyphenoxy)benzene

C86H50N4O14

C86H50N4O14

Conditions
ConditionsYield
Stage #1: 4,4'-bis(4-aminophenoxy)biphenyl; 1,3-bis(3,4-dicarboxyphenoxy)benzene In 1-methyl-pyrrolidin-2-one
Stage #2: phthalic anhydride
Stage #3: Heating;
phthalic anhydride
85-44-9

phthalic anhydride

4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

dianhydride of bis(3,4-dicarboxyphenyl)resorcinol ether

dianhydride of bis(3,4-dicarboxyphenyl)resorcinol ether

polymer, Mw 2.4E4; monomer(s): 1,3-bis(3,4-dicarboxyphenoxy)benzene dianhydride; 4,4\-bis(4-aminophenoxy)biphenyl; phthalic anhydride

polymer, Mw 2.4E4; monomer(s): 1,3-bis(3,4-dicarboxyphenoxy)benzene dianhydride; 4,4\-bis(4-aminophenoxy)biphenyl; phthalic anhydride

Conditions
ConditionsYield
Stage #1: 4,4'-bis(4-aminophenoxy)biphenyl; dianhydride of bis(3,4-dicarboxyphenyl)resorcinol ether
Stage #2: phthalic anhydride at 280℃;
phthalic anhydride
85-44-9

phthalic anhydride

4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

dianhydride of bis(3,4-dicarboxyphenyl)resorcinol ether

dianhydride of bis(3,4-dicarboxyphenyl)resorcinol ether

polymer, Mw 1.3E4; monomer(s): 1,3-bis(3,4-dicarboxyphenoxy)benzene dianhydride; 4,4\-bis(4-aminophenoxy)biphenyl; phthalic anhydride

polymer, Mw 1.3E4; monomer(s): 1,3-bis(3,4-dicarboxyphenoxy)benzene dianhydride; 4,4\-bis(4-aminophenoxy)biphenyl; phthalic anhydride

Conditions
ConditionsYield
Stage #1: 4,4'-bis(4-aminophenoxy)biphenyl; dianhydride of bis(3,4-dicarboxyphenyl)resorcinol ether
Stage #2: phthalic anhydride at 280℃;
phthalic anhydride
85-44-9

phthalic anhydride

4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

dianhydride of bis(3,4-dicarboxyphenyl)resorcinol ether

dianhydride of bis(3,4-dicarboxyphenyl)resorcinol ether

polymer, Mw 0.8E4; monomer(s): 1,3-bis(3,4-dicarboxyphenoxy)benzene dianhydride; 4,4\-bis(4-aminophenoxy)biphenyl; phthalic anhydride

polymer, Mw 0.8E4; monomer(s): 1,3-bis(3,4-dicarboxyphenoxy)benzene dianhydride; 4,4\-bis(4-aminophenoxy)biphenyl; phthalic anhydride

Conditions
ConditionsYield
Stage #1: 4,4'-bis(4-aminophenoxy)biphenyl; dianhydride of bis(3,4-dicarboxyphenyl)resorcinol ether
Stage #2: phthalic anhydride at 280℃;
phthalic anhydride
85-44-9

phthalic anhydride

4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

C40H24N2O6

C40H24N2O6

Conditions
ConditionsYield
Stage #1: phthalic anhydride; 4,4'-bis(4-aminophenoxy)biphenyl In 1-methyl-pyrrolidin-2-one
Stage #2: Heating;
4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

dianhydride of bis(3,4-dicarboxyphenyl)resorcinol ether

dianhydride of bis(3,4-dicarboxyphenyl)resorcinol ether

polymer, Mw 2.0E4; monomer(s): 1,3-bis(3,4-dicarboxyphenoxy)benzene dianhydride; 4,4\-bis(4-aminophenoxy)biphenyl

polymer, Mw 2.0E4; monomer(s): 1,3-bis(3,4-dicarboxyphenoxy)benzene dianhydride; 4,4\-bis(4-aminophenoxy)biphenyl

Conditions
ConditionsYield
Stage #1: 4,4'-bis(4-aminophenoxy)biphenyl; dianhydride of bis(3,4-dicarboxyphenyl)resorcinol ether
Stage #2: at 280℃;
4,4'-bis(4-aminophenoxy)biphenyl
13080-85-8

4,4'-bis(4-aminophenoxy)biphenyl

dianhydride of bis(3,4-dicarboxyphenyl)resorcinol ether

dianhydride of bis(3,4-dicarboxyphenyl)resorcinol ether

polymer, Mw 2.9E4; monomer(s): 1,3-bis(3,4-dicarboxyphenoxy)benzene dianhydride; 4,4\-bis(4-aminophenoxy)biphenyl

polymer, Mw 2.9E4; monomer(s): 1,3-bis(3,4-dicarboxyphenoxy)benzene dianhydride; 4,4\-bis(4-aminophenoxy)biphenyl

Conditions
ConditionsYield
Stage #1: 4,4'-bis(4-aminophenoxy)biphenyl; dianhydride of bis(3,4-dicarboxyphenyl)resorcinol ether
Stage #2: at 280℃;

13080-85-8Relevant articles and documents

Synthesis, Characterization, and Phytotoxic and Antifungal Activities of Biphenyl Derivatives

Ali,Irshad,Asghar

, p. 2177 - 2182 (2018/12/11)

Three series of biphenyl derivatives are synthesized, characterized and evaluated for Lemna minor phytotoxicity and antifungal activity. The synthetic biphenyl analogues 2c and 6c demonstrate significant activity, while compounds 4b and 6b demonstrate hig

Functionalized Photoreactive Compounds

-

, (2008/12/08)

The present invention concerns functionalized photoreactive compounds of formula (I), that are particularly useful in materials for the alignment of liquid crystals. Due to the adjunction of an electron withdrawing group to specific molecular systems bearing an unsaturation directly attached to two unsaturated ring systems, exceptionally high photosensitivities, excellent alignment properties as well as good mechanical robustness could be achieved in materials comprising said functionalized photoreactive compounds of the invention.

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