120-21-8Relevant articles and documents
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Boessneck
, p. 366 (1886)
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Self-assembly of a series of thiocyanate complexes with high two-photon absorbing active in near-IR range and bioimaging applications
Li, Dandan,Zhang, Qiong,Wang, Xuchun,Li, Shengli,Zhou, Hongping,Wu, Jieying,Tian, Yupeng
, p. 175 - 183 (2015)
Abstract A series of novel complexes bearing high fluorescence quantum yields and showing the peak two-photon absorption (2 PA) cross-sections in the near-infrared region, Zn(SCN)2L2(1), [Cd(SCN)2L2]n(2), Co(SCN)2L4(3), Ni(SCN)2L4(4), [CdHgL2(SCN)4]n(5) and [MnHg(SCN)4L2]n(6), containing functional chromophore (L = (E)-(4-diethyl anilinostyryl)pyridine), were synthesized in high yields. Crystal structures of all the complexes were confirmed. Hetero-metal complexes (5, 6: L:M = 1:1) present much higher two-photon absorption (2 PA) cross-sections (σ) in comparison with those of the homo-metal complexes (L:M = 4:1 in 3 and 4, L:M = 2:1 in 1 and 2) and the free ligand (L) which may due to the fact that the hetero-metal complexes have more bridged anions (SCN-), conjugated subunits -[Hg(SCN)2M]- and -[Hg2(SCN)4M2]-. In addition, the results revealed that 2 PA response was much enhanced for the Zn(SCN)2L2 and two-photon fluorescence cell imaging experiment proved its potential application.
Detection living body Fe2 + Double-photon fluorescence probe as well as preparation method and application thereof
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Paragraph 0042-0045; 0051-0054; 0060-0063, (2021/11/19)
The invention relates to a pyrimidine-based dye which can be quickly regulated and controlled by light. Sensitive detection living body Fe2 + A double-photon fluorescence probe belongs to the field of organic fluorescent probes. The fluorescent probe is PyFe fluorescence probe, and the structural formula of PyFe fluorescence probe is as shown in formula (I). Fe In vivo can be accurately detected by the fluorescent probe. 2 + , Interference of other ionic amino acids in the cells is avoided. The probe has very fast response rate and high ion selectivity, can realize naked eye detection in vitro and also has good biocompatibility. The fluorescence confocal imaging experiment shows that the probe has good cell permeability, does not have toxic or side effects on cells and organisms, and has dual photonicity, so that the depth imaging of living animals or tissues can be realized.
A process for preparing a broad pH fluorescent probe of the organic compound and use thereof (by machine translation)
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Paragraph 0130; 0131, (2018/04/03)
The present invention discloses a process for the preparation of a wide range of fluorescent probe in the pH of the organic compound, the organic compound can be produced according to the actual need to carry out any proportion of combination, and can be fixed in the hydrophilic high polymer further preparing and detecting water environment acidity and alkalinity of the product. The product can be realized to the pH value of the continuous measuring, thereby greatly improving the efficiency, sensitivity and repeatability. (by machine translation)