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CAS No.: | 813-99-0 |
---|---|
Name: | PENTAERYTHRITOL TRICHLOROHYDRIN |
Article Data: | 23 |
Molecular Structure: | |
Formula: | C5H9 Cl3 O |
Molecular Weight: | 191.485 |
Synonyms: | 2,2-Bis(chloromethyl)-3-chloro-1-propanol;2,2-Bis(chloromethyl)-3-chloropropanol; 3-Chloro-2,2-bis(chloromethyl)-1-propanol;NSC 405661; NSC 524090; Pentaerythritol trichloride; Pentaerythritoltrichlorohydrin; Pentaerythrityl trichlorohydrin |
Density: | 1.341 g/cm3 |
Boiling Point: | 316.8 °C at 760 mmHg |
Flash Point: | 145.4 °C |
PSA: | 20.23000 |
LogP: | 1.68150 |
Conditions | Yield |
---|---|
With pyridine; thionyl chloride at 65 - 130℃; for 22h; | 73% |
With pyridine; thionyl chloride | 50% |
With hydrogenchloride; formic acid; benzene at 160℃; |
Pentaerythritol
A
2,2-bis(chloromethyl)-1,3-propanediol
B
3-chloro-(2,2-chloromethyl)propan-1-ol
Conditions | Yield |
---|---|
With hydrogenchloride at 185℃; | |
With pyridine; thionyl chloride anfangs unter Eiskuehlung,dann bei Siedetemperatur; |
acetic acid-(3-chloro-2,2-bis-chloromethyl-propyl ester)
3-chloro-(2,2-chloromethyl)propan-1-ol
Conditions | Yield |
---|---|
With sodium hydroxide | |
With hydrogenchloride |
3-chloro-2,2-bis-chloromethyl-propionic acid methyl ester
3-chloro-(2,2-chloromethyl)propan-1-ol
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride; diethyl ether |
Conditions | Yield |
---|---|
With diethylaluminium chloride |
Pentaerythritol
A
2,2-bis(chloromethyl)-1,3-propanediol
B
pentaerythrityl tetrachloride
C
3-chloro-(2,2-chloromethyl)propan-1-ol
Conditions | Yield |
---|---|
With pyridine; thionyl chloride for 14h; Heating; Yield given. Yields of byproduct given; |
Pentaerythritol
A
pentaerythrityl tetrachloride
B
3-chloro-(2,2-chloromethyl)propan-1-ol
Conditions | Yield |
---|---|
With pyridine; thionyl chloride at 120 - 130℃; Yield given. Yields of byproduct given; | |
With pyridine; thionyl chloride at 65 - 95℃; |
pyridine
thionyl chloride
Pentaerythritol
A
2,2-bis(chloromethyl)-1,3-propanediol
B
pentaerythrityl tetrachloride
C
3-chloro-(2,2-chloromethyl)propan-1-ol
Conditions | Yield |
---|---|
anfangs unter Eiskuehlung, dann bei Siedetemperatur; |
3-chloro-(2,2-chloromethyl)propan-1-ol
allyl bromide
3-(3-chloro-2,2-bis-chloromethyl-propoxy)-propene
Conditions | Yield |
---|---|
With potassium hydroxide In dimethyl sulfoxide at 60℃; | 82% |
Conditions | Yield |
---|---|
With potassium hydroxide In ethanol for 72h; Heating / reflux; | 80% |
With potassium hydroxide In ethanol for 0.5h; Reflux; | 74% |
With potassium hydroxide |