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Basic Information
CAS No.: 764-01-2
Name: 2-Butyn-1-ol
Article Data: 49
Molecular Structure:
Molecular Structure of 764-01-2 (2-Butyn-1-ol)
Formula: C4H6O
Molecular Weight: 70.091
Synonyms: 1-Hydroxybut-2-yne;2-Butynol;NSC 222371;2-Butynyl alcohol;
EINECS: 212-113-4
Density: 0.929 g/cm3
Melting Point: - 2.2 °C(lit.)
Boiling Point: 148 °C at 760 mmHg
Flash Point: 51.7 °C
Appearance: clear colourless to light yellow liquid
Hazard Symbols: IrritantXi,FlammableF
Risk Codes: 10-43-52/53-36/37/38
Safety: 36/37-26-16
Transport Information: UN 1987 3/PG 3
PSA: 20.23000
LogP: 0.00200
Synthetic route
107-19-7

propargyl alcohol

74-88-4

methyl iodide

764-01-2

methyl propargyl alcohol

Conditions
ConditionsYield
With lithium; ferric nitrate In ammonia at -50℃; for 2h;95%
With lithium amide In ammonia78%
Multistep reaction;
Stage #1: methyl iodide With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine at 25℃; for 0.166667h; Inert atmosphere;
Stage #2: propargyl alcohol at 25℃; for 10h; Inert atmosphere;
39637-48-4

2-(but-2-ynyloxy)-tetrahydro-2H-pyran

764-01-2

methyl propargyl alcohol

Conditions
ConditionsYield
With toluene-4-sulfonic acid In methanol95%
With toluene-4-sulfonic acid In methanol59%
764-01-2

methyl propargyl alcohol

Conditions
ConditionsYield
With sodium hydroxide In cyclohexane; water at 65 - 72℃; for 8h;88.1%
With potassium hydroxide; tetra-(n-butyl)ammonium iodide In hexane for 12h; Heating;50%
With ammonia; sodium; ferric nitrate for 14h;47%
With ammonia; sodium amide Behandeln des Reaktions-Loesung mit NH4Cl;
With ammonia; sodium amide
50965-89-4

dilithium salt of propargyl alcohol

74-88-4

methyl iodide

764-01-2

methyl propargyl alcohol

Conditions
ConditionsYield
85%
97231-46-4

1-(methoxymethoxy)but-2-yne

764-01-2

methyl propargyl alcohol

Conditions
ConditionsYield
With bismuth(III) chloride; water In acetonitrile at 50℃; for 3h;85%
83591-03-1

(but-2-yn-1-yloxy)(tert-butyl)dimethylsilane

764-01-2

methyl propargyl alcohol

Conditions
ConditionsYield
With P(MeNCH2CH2)3N In dimethyl sulfoxide at 80℃; for 36h; desilylation;83%
50-00-0

formaldehyd

463-49-0

1,2-propanediene

5389-87-7

1-chloro-3,7-dimethylocta-2,6-diene

A

764-01-2

methyl propargyl alcohol

B

16933-56-5

(6E)-7,11-dimethyldodeca-6,10-dien-2-yn-1-ol

Conditions
ConditionsYield
Stage #1: 1,2-propanediene With n-butyllithium In diethyl ether; hexane at -78 - -15℃; for 1.75h; Inert atmosphere;
Stage #2: 1-chloro-3,7-dimethylocta-2,6-diene In diethyl ether; hexane at -15℃; for 5.05h; Inert atmosphere;
Stage #3: formaldehyd Further stages;
A n/a
B 68%
50-00-0

formaldehyd

16466-97-0, 13254-27-8

1-propynylmagnesium bromide

764-01-2

methyl propargyl alcohol

Conditions
ConditionsYield
With diethyl ether
37428-46-9

(Z)-3-chloro-2-but-en-1-ol

764-01-2

methyl propargyl alcohol

Conditions
ConditionsYield
With potassium hydroxide
With potassium hydroxide
With sodium hydroxide
4089-67-2

2,3-dichloro-1-butanol

764-01-2

methyl propargyl alcohol

Conditions
ConditionsYield
With ammonia; sodium amide
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    2-Butyn-1-ol Basic information Product Name: 2-Butyn-1-ol Synonyms: 2-butyn-1-0l;2-Butynol;2-Butynyl alcohol;BUT-2-IN-1-OL;HYDROXYMETHYLMETHYLACETYLENE;2-BUTYN-1-OL 99%;1-hydroxy-2-butyne;2-BUTYNE-1-OL CAS: 764-01-2 MF: C4H6O MW: 70.0

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  • 2-Butyn-1-ol

  • Casno:

    764-01-2

    2-Butyn-1-ol

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    Name: 2-Butyn-1-ol. Synonym:2-butyn-1-0l;2-Butynol;2-Butynylalcohol;BUT-2-IN-1-OL;HYDROXYMETHYLMETHYLACETYLENE;2-BUTYN-1-OL99%;1-hydroxy-2-butyne;2-BUTYNE-1-OL CAS No: 764-01-2. Molecular formula: C4H6O. Molecular weight: 70.09. Appearanc

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  • 2-Butyn-1-ol cas no. 764-01-2 97%+%

  • Casno:

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    2-Butyn-1-ol cas no. 764-01-2 97%+%

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  • Casno:

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    2-Butyn-1-ol

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Chemistry

The Molecular formula of 2-BUTYN-1-OL(764-01-2): C4H6O
The Molecular Weight of 2-BUTYN-1-OL(764-01-2):70.09
The Molecular Structure of 2-BUTYN-1-OL(764-01-2):
EINECS: 212-113-4
Melting point: -2.2 °C(lit.)
Boiling Point: 148 °C at 760 mmHg 
Flash Point: 51.7 °C 
Index of Refraction: 1.446 
Molar Refractivity: 20.12 cm
Molar Volume: 75.3 cm3 
Polarizability: 7.97 10-24 cm
Surface Tension: 37.2 dyne/cm 
Density: 0.929 g/cm3 
Enthalpy of Vaporization: 44.84 kJ/mol 
Vapour Pressure: 1.67 mmHg at 25°C 
storage temp.: Refrigerator
Stability: Stable. Flammable.
Appearance: liquid
BRN: 1733676
IUPAC Name: but-2-yn-1-ol
Synonyms: 2-butyn-1-0l;2-Butynol;HYDROXYMETHYLMETHYLACETYLENE;CH3CequivCCH2OH;BUT-2-IN-1-OL;2-BUTYNE-1-OL;2-Butynyl alcohol;But-2-yn-1-ol;

Safety Profile

The Hazard Codes of 2-BUTYN-1-OL(764-01-2):   Xi,   F
Hazard Note: Irritant
HazardClass: 3
The Risk Statements information of 2-BUTYN-1-OL(764-01-2):
10:  Flammable 
43:  May cause sensitization by skin contact 
36/37/38:  Irritating to eyes, respiratory system and skin 
52/53:  Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment 
The Safety Statements information of 2-BUTYN-1-OL(764-01-2):
16:  Keep away from sources of ignition - No smoking 
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
36/37:  Wear suitable protective clothing and gloves 
RIDADR: UN 1987 3/PG 3
WGK Germany: 3
PackingGroup: III
HS Code: 29052990