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Basic Information
| CAS No.: | 6362-80-7 |
|---|---|
| Name: | 4-Methyl-2,4-diphenyl-1 -pentene |
| Article Data: | 67 |
| Molecular Structure: | |
|
|
|
| Formula: | C18H20 |
| Molecular Weight: | 236.357 |
| Synonyms: | 1-Pentene,4-methyl-2,4-diphenyl- (6CI,7CI,8CI); 2,4-Diphenyl-4-methyl-1-pentene;4-Methyl-2,4-diphenyl-1-pentene; Nofmer MSD; a-(2-Methyl-2-phenylpropyl)styrene |
| EINECS: | 228-846-8 |
| Density: | 0.99 |
| Boiling Point: | 161 ºC (5 mmHg) |
| Flash Point: | >110 ºC |
| Hazard Symbols: |
|
| Risk Codes: | R36/37 |
| Safety: | S26;S36 |
| PSA: | 0.00000 |
| LogP: | 5.06770 |
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Synthetic route
Conditions
| Conditions | Yield |
|---|---|
| With di-tert-butyl peroxide; potassium carbonate at 120℃; for 93h; | 100% |
| With di-tert-butyl peroxide; potassium carbonate at 120℃; for 93h; Degassed pressure tube; | 100% |
| With triethyl borane; oxygen at 80℃; for 12h; | 35 %Chromat. |
- 98-83-9
isopropenylbenzene
A
- 3910-35-8
1,1,3-trimethyl-3-phenylindane
B
- 6362-80-7
2,4-diphenyl-4-methyl-pent-1-ene
C
- 22768-22-5, 22768-23-6, 6258-73-7
4-methyl-2,4-diphenylpent-2-ene
Conditions
| Conditions | Yield |
|---|---|
| thiol-modified Al-loaded mesoporous silica In toluene at 120℃; for 2h; | A 97.1% B 0.7% C 1% |
| thiol-modified Al-loaded mesoporous silica In toluene at 80℃; for 2h; | A 37.5% B 16.9% C 42.8% |
| nafion resin; silica gel In various solvent(s) at 50℃; under 760 Torr; Product distribution; Rate constant; var. soluble liquid acids and resin-based solid acids as catalysts; var. time and solv.; |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| With indium(III) bromide In dichloromethane at 0℃; for 2h; | 90% |
| With ruthenium trichloride In tetrahydrofuran | 78% |
| With C13H17N3Ni(1+)*C32H12BF24(1-) In 1,2-dichloro-ethane at 60℃; for 4h; Inert atmosphere; | 72% |
Conditions
| Conditions | Yield |
|---|---|
| With bismuth(III) bromide In dichloromethane at -78 - 0℃; Inert atmosphere; | 88% |
| With acetic anhydride; cerium triflate In acetonitrile at 20℃; for 24h; | 84% |
| With iron(III) p-toluenesulfonate hexahydrate; acetic anhydride In acetonitrile | 26% |
| Multi-step reaction with 2 steps 1: p-toluenesulfonic acid / benzene 2: 90 percent / InBr3 / CH2Cl2 / 2 h / 0 °C View Scheme |
- 98-82-8
Isopropylbenzene
- 1608461-37-5
2-((2-phenylallyl)oxy)isoindoline-1,3-dione
A
- 524-38-9
N-hydroxyphthalimide
B
- 6362-80-7
2,4-diphenyl-4-methyl-pent-1-ene
Conditions
| Conditions | Yield |
|---|---|
| With di-tert-butyl peroxide In neat (no solvent) at 120℃; for 29h; | A n/a B 76% |
...Expand
- 98-82-8
Isopropylbenzene
- 1608461-37-5
2-((2-phenylallyl)oxy)isoindoline-1,3-dione
- 6362-80-7
2,4-diphenyl-4-methyl-pent-1-ene
Conditions
| Conditions | Yield |
|---|---|
| With di-tert-butyl peroxide In neat (no solvent) at 120℃; for 29h; Sealed tube; | 76% |
| With di-tert-butyl peroxide at 120℃; Temperature; Sealed tube; |
- 934-53-2
cumenyl chloride
- 557-34-6
zinc diacetate
A
- 617-94-7
1-methyl-1-phenylethyl alcohol
B
- 3425-72-7
cumyl acetate
C
- 6362-80-7
2,4-diphenyl-4-methyl-pent-1-ene
D
- 98-83-9
isopropenylbenzene
Conditions
| Conditions | Yield |
|---|---|
| In acetic acid at 10 - 15℃; for 2h; | A 3.4 g B 72% C 5.9 g D 2.9 g |
...Expand
- 617-94-7
1-methyl-1-phenylethyl alcohol
A
- 3910-35-8
1,1,3-trimethyl-3-phenylindane
B
- 6362-80-7
2,4-diphenyl-4-methyl-pent-1-ene
C
- 68305-40-8
1,1-dimethyl-3-(2-methyl-2-phenylpropyl)-3-phenyl-2,3-dihydro-1H-indene
Conditions
| Conditions | Yield |
|---|---|
| With iron(III) chloride; 1,1,1,3',3',3'-hexafluoro-propanol; nitric acid at 20℃; for 3h; Catalytic behavior; | A 7 %Spectr. B 62% C 9 %Spectr. |
...Expand
- 617-94-7
1-methyl-1-phenylethyl alcohol
A
- 6362-80-7
2,4-diphenyl-4-methyl-pent-1-ene
B
- 98-83-9
isopropenylbenzene
Conditions
| Conditions | Yield |
|---|---|
| With phosphoric acid; acetic anhydride for 48h; Ambient temperature; | A 23% B 60% |
| With o-benzenedisulfonimide; acetic anhydride at 20℃; | A 45% B 31% |
Conditions
| Conditions | Yield |
|---|---|
| zinc chloride diethyl ether In dichloromethane at -78℃; for 17h; | 58% |
Downstream Products
