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Basic Information
CAS No.: 5707-96-0
Name: Justicidin B
Article Data: 17
Molecular Structure:
Molecular Structure of 5707-96-0 (Justicidin B)
Formula: C21H16O6
Molecular Weight: 364.354
Synonyms: 9-(3,4-dimethoxy-phenyl)-8H-furo[3',4':6,7]naphtho[2,3-d][1,3]dioxol-6-one;UNII-RQQ8T34V5F;9-(3,4-dimethoxyphenyl)furo[3',4':6,7]naphtho[2,3-d][1,3]dioxol-6(8h)-one;Retrochinensin;Retrochinesin;
Density: 1.376g/cm3
Boiling Point: 593.2°Cat760mmHg
Flash Point: 262.2°C
PSA: 63.22000
LogP: 3.92310
Synthetic route
103844-18-4, 118626-89-4

4-(3',4'-dimethoxyphenyl)-3-hydroxymethyl-6,7-methylenedioxy-3,4-dihydro-2-naphthoic acid γ-lactone

5707-96-0

retrochinensin

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In chloroform; benzene for 48h; Heating;100%
42923-60-4

2,3-bis-(hydroxymethyl)-6,7-methylenedioxy-1-(3',4'-dimethoxyphenyl)-naphthalene

5707-96-0

retrochinensin

Conditions
ConditionsYield
With 1-Phenylbut-1-en-3-one; dihydridotetrakis(triphenylphosphine)ruthenium In toluene for 10h; Heating;94%
With manganese(IV) oxide In dichloromethane at 20℃; for 48h;91%
42923-60-4

2,3-bis-(hydroxymethyl)-6,7-methylenedioxy-1-(3',4'-dimethoxyphenyl)-naphthalene

A

31888-76-3

1-(3,4-dimethoxyphenyl)-3-hydroxymethyl-6,7-methylenedioxynaphthalene-2-carboxylic acid lactone

B

5707-96-0

retrochinensin

Conditions
ConditionsYield
With barium permanganate In dichloromethane at 20℃; for 48h;A 19%
B 80%
With bis(pyridine)silver permanganate In benzene for 2h; Heating;A 18.2%
B 56.6%
With pyridinium chlorochromate In chloroform for 12h; Ambient temperature;A 53.2%
B 25.3%
With silica gel; silver carbonate In benzene for 3h; Heating;A 14 mg
B 58 mg
289622-32-8

6,7-methylenedioxy-1-(3,4-dimethoxyphenyl)naphthalene-2,3-dicarboxylic acid 2-ethyl ester

5707-96-0

retrochinensin

Conditions
ConditionsYield
With lithium borohydride; sodium hydride In tetrahydrofuran; 1,4-dioxane for 28h; Heating;72%
72622-61-8

α-(trans-3',4'-methylenedioxybenzylidene)-β-(3,4-dimethoxybenzyl)-γ-butyrolactone

5707-96-0

retrochinensin

Conditions
ConditionsYield
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In benzene for 24h; Heating;70%
103844-12-8

erythro-3-<3'',4''-dimethoxy-α,α-bis(phenylthio)benzyl>-2-(α-hydroxy-3',4'-methylenedioxybenzyl)-γ-butyrolactone

5707-96-0

retrochinensin

Conditions
ConditionsYield
With trifluoroacetic acid for 2h; Heating;62%
With trifluoroacetic acid60%

C21H16O6

A

17951-19-8

justicidin B

B

5707-96-0

retrochinensin

Conditions
ConditionsYield
In dichloromethane at 0℃; for 0.166667h; Diels-Alder Cycloaddition; Flow reactor; Irradiation; regioselective reaction;A 17.3%
B 52.2%
42923-53-5

1-(3',4'-dimethoxyphenyl)-6,7-methylenedioxynaphthalene-2,3-dicarboxylic anhydride

5707-96-0

retrochinensin

Conditions
ConditionsYield
With sodium tetrahydroborate49.5%
57134-53-9

3,4-methylenedioxyphenylethyne

124-38-9

carbon dioxide

1184406-44-7

3,4-dimethoxyphenylpropargyl chloride

A

17951-19-8

justicidin B

B

5707-96-0

retrochinensin

Conditions
ConditionsYield
With 18-crown-6 ether; silver(I) iodide In N,N-dimethyl acetamide at 100℃; under 760.051 Torr; for 5h; Molecular sieve;A 16%
B 16%
103844-12-8

erythro-3-<3'',4''-dimethoxy-α,α-bis(phenylthio)benzyl>-2-(α-hydroxy-3',4'-methylenedioxybenzyl)-γ-butyrolactone

A

5707-96-0

retrochinensin

103865-35-6, 118917-44-5

threo-3-(3'',4''-dimethoxybenzoyl)-2-(3',4'-methylenedioxy-α-phenylthiobenzyl)butyrolactone

103865-35-6, 118917-44-5

erythro-3-(3'',4''-dimethoxybenzoyl)-2-(3',4'-methylenedioxy-α-phenylthiobenzyl)butyrolactone

Conditions
ConditionsYield
With tin(IV) chloride In dichloromethane for 1h; Product distribution; Ambient temperature; attempted cyclisations of further derivatives with various acids;
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  • Justicidin B CAS NO.5707-96-0

  • Casno:

    5707-96-0

    Justicidin B CAS NO.5707-96-0

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Justicidin B CAS NO.5707-96-0Appearance:off-white fine crystalline powder Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier l

    Nanjing Raymon Biotech Co., Ltd. is specialized in developing and marketing middle & high level pharmaceutical intermediates. We are supplying different categories of high-quality

  • Nanjing Raymon Biotech Co., Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-025-52181296

    Address:Block B, No. 918, Shuanglong Avenue

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  • Justicidin B CAS NO.5707-96-0

  • Casno:

    5707-96-0

    Justicidin B CAS NO.5707-96-0

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Justicidin B CAS NO.5707-96-0Appearance:off-white fine crystalline powder Storage:Dry and ventilated Package:Standard or as customer's require Application:intermediates Transportation:Delivery by EMS, DHL, FEDEX, UPS, TNT

    Shanghai PengMo Biotechnology Co., Ltd. is engaging in researching, developing, manufacturing and exporting advanced pharmaceutical intermediates and other fine chemicals. Our comp

  • Shanghai PengMo Biotechnology Co.,Ltd

     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:86-13052359378

    Address:No.218 Hai Qu Road.Shanghai.China

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  • Justicidin B CAS NO.5707-96-0

  • Casno:

    5707-96-0

    Justicidin B CAS NO.5707-96-0

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Justicidin B CAS NO.5707-96-0 Application:Justicidin B CAS NO.5707-96-0

    Hangzhou Fenjunchem Co.,Ltd dedicated to the development, production and marketing of chemicals which is specialized in Organic compounds; Active Pharmaceutical Ingredient(s); Nutr

  • Hangzhou Fenjun Chemical Co Ltd.

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-0571-56263321

    Address:hangzhou

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  • 5707-96-0

  • Casno:

    5707-96-0

    5707-96-0

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Supply top quality products with a reasonable price Application:api

    Hebei Ruishun Trade Co.,Ltd registered capital one million, we have a production of pharmaceutical raw materials, pharmaceutical raw materials factory reagent r&d center, we do

  • Hebei Ruishun Trade Co.,Ltd

    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-311-68037669

    Address:WanDa commerce building ,yuhua district

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