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| CAS No.: | 5550-12-9 |
|---|---|
| Name: | Guanosine 5'-monophosphate disodium salt |
| Article Data: | 3 |
| Molecular Structure: | |
|
|
|
| Formula: | C10H12N5Na2O8P |
| Molecular Weight: | 407.187 |
| Synonyms: | 5'-Guanylicacid, disodium salt (7CI,8CI,9CI);5'-GMP disodium salt;Disodium 5'-GMP;Disodium 5'-guanylate;Disodium GMP;Disodium guanosine 5'-monophosphate;Disodium guanosine 5'-phosphate;Disodium guanylate;E 627;GMP disodium salt;GMP sodium salt;Guanosine 5'-monophosphate disodium salt;Guanosine5'-phosphate disodium salt;Guanylic acid sodium salt;NSC 20265;Sodium5'-guanylate;Sodium GMP;Sodium guanosine 5'-monophosphate;Sodium guanylate; |
| EINECS: | 226-914-1 |
| Melting Point: | 300 °C |
| Boiling Point: | 890.2oC at 760 mmHg |
| Flash Point: | 492.2oC |
| Solubility: | >50 g/L in water |
| Appearance: | White crystalline powder |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | 36/37/38 |
| Safety: | 22-24/25-36/37/39-27-26 |
| PSA: | 221.51000 |
| LogP: | -1.11210 |
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| Conditions | Yield |
|---|---|
| With trimethyl phosphite; water; sodium chloride; magnesium chloride; N-2-hydroxyethylpiperazine-N'-2-ethanesulfonic acid In water-d2 at 25℃; Kinetics; |
- 80242-42-8
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B
- 5550-12-9
guanosine 5'-monophosphate disodium
| Conditions | Yield |
|---|---|
| With trimethyl phosphite; water; sodium chloride; magnesium chloride; N-2-hydroxyethylpiperazine-N'-2-ethanesulfonic acid In water-d2 at 25℃; Kinetics; |
- 5550-12-9
guanosine 5'-monophosphate disodium
| Conditions | Yield |
|---|---|
| With water; zinc(II) cation pH=5.5; |
| Conditions | Yield |
|---|---|
| With Dowex 50W×8 resin In water at 20℃; for 0.5h; | 99% |
| With Dowex 50WX-8 200 mesh, H+ |
| Conditions | Yield |
|---|---|
| With 2,2'-dipyridyldisulphide; triphenylphosphine In N,N-dimethyl-formamide at 20℃; | 90% |
| Conditions | Yield |
|---|---|
| In dimethyl sulfoxide at 20℃; for 24h; | 81% |
- 15663-27-1
cisplatin
- 5550-12-9
guanosine 5'-monophosphate disodium
| Conditions | Yield |
|---|---|
| In water mixture is heated at 50°C for about 3-5 h with stirring; the clear soln. is left overnight at room temp.;; concn. under vacuum; pptn. with acetone, then with ether; white ppt. isfiltered off, washed with acetone, then with ether and dried in air;; | 75% |
| In water stirring Pt-complex with 2 equiv. of ligand (room temp., 3 h, in dark); |
| Conditions | Yield |
|---|---|
| In dimethyl sulfoxide at 20℃; for 24h; | 75% |
| Conditions | Yield |
|---|---|
| In dimethyl sulfoxide at 20℃; for 24h; | 71% |
| Conditions | Yield |
|---|---|
| In dimethyl sulfoxide at 20℃; for 24h; | 70% |
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Chemistry
IUPAC Name:disodium [5-(2-amino-6-oxo-3H-purin-9-yl)-3,4-dihydroxyoxolan-2-yl]methyl phosphate
Molecular Formula:C10H12N5Na2O8P
Molecular Weight:407.184281 g/mol
Appearance:White crystalline powder
Melting Point:300 °C
Solubility:slightly soluble in ethanol, acetone and ether
storage temp.:2-8 °C
Water Solubility:>50 g/L
FEMA:3668
EINECS:226-914-1
Synonyms of GUANYLIC ACID SODIUM SALT(5550-12-9):
GMP-5;5’-gmpdisodiumsalt;disodium5’-gmp;disodiumgmp;gmpsodiumsalt;sodium5’-guanylate;sodiumgmp;sodiumguanosine5’-monophosphate;Guanosine 5'-monophosphate disodium salt
Categories of GUANYLIC ACID SODIUM SALT(5550-12-9):
Pharmaceutical Intermediates;Biochemistry;Nucleosides, Nucleotides & Related Reagents;Nucleotides and their analogs;Nucleic acids
Uses
Toxicity Data With Reference
| 1. | cyt-ham:fbr 1 g/L | FCTOD7 Food and Chemical Toxicology. 22 (1984),623. | ||
| 2. | ipr-rat LD50:3880 mg/kg | AJINO* Ajinomoto Co., Inc. (9W. 57th St., Suite 4625, New York, NY 10019) | ||
| 3. | scu-rat LD50:3400 mg/kg | AJINO* Ajinomoto Co., Inc. (9W. 57th St., Suite 4625, New York, NY 10019) | ||
| 4. | ivn-rat LD50:2720 mg/kg | AJINO* Ajinomoto Co., Inc. (9W. 57th St., Suite 4625, New York, NY 10019) | ||
| 5. | orl-mus LD50:15 g/kg | AJINO* Ajinomoto Co., Inc. (9W. 57th St., Suite 4625, New York, NY 10019) | ||
| 6. | ipr-mus LD50:5010 mg/kg | AJINO* Ajinomoto Co., Inc. (9W. 57th St., Suite 4625, New York, NY 10019) | ||
| 7. | scu-mus LD50:5050 mg/kg | AJINO* Ajinomoto Co., Inc. (9W. 57th St., Suite 4625, New York, NY 10019) | ||
| 8. | ivn-mus LD50:3580 mg/kg | AJINO* Ajinomoto Co., Inc. (9W. 57th St., Suite 4625, New York, NY 10019) |
Consensus Reports
Safety Profile
Safety Information of GUANYLIC ACID SODIUM SALT(5550-12-9):
Hazard Codes:Xi 
Risk Statements:36/37/38
36/37/38:Irritating to eyes, respiratory system and skin
Safety Statements:22-24/25-36/37/39-27-26
22:Do not breathe dust
24/25:Avoid contact with skin and eyes
36/37/39:Wear suitable protective clothing, gloves and eye/face protection
27:Take off immediately all contaminated clothing
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
WGK Germany:2
RTECS:MF9290000
Moderately toxic by intraperitoneal, subcutaneous, and intravenous routes. Mildly toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of POx, NOx, and Na2O.