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Basic Information
CAS No.: 4125-43-3
Name: 1-ALLYLOXY-2-METHOXY-BENZENE
Article Data: 49
Molecular Structure:
Molecular Structure of 4125-43-3 (1-ALLYLOXY-2-METHOXY-BENZENE)
Formula: C10H12O2
Molecular Weight: 164.204
Synonyms: 2-Allyloxyanisole;Guaiacol allyl ether;O-allyl guaiacol;o-Methoxyphenyl allyl ether;Allyl o-methoxyphenyl ether;
Density: 0.991g/cm3
Boiling Point: 226.7°Cat760mmHg
Flash Point: 81°C
PSA: 18.46000
LogP: 2.26000
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Synthetic route
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allyl bromide

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O-allyl guaiacol

Conditions
ConditionsYield
With potassium carbonate In acetone at 20℃; Reflux;100%
With potassium carbonate; potassium iodide In acetone for 18h; Reflux;100%
With potassium carbonate99%
35466-83-2

allyl methyl carbonate

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2-methoxy-phenol

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O-allyl guaiacol

Conditions
ConditionsYield
With triphenylphosphine In water at 80℃; for 2h; Tsuji-Trost Allylation;92%
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sodium 2-methoxyphenolate

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allyl bromide

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O-allyl guaiacol

Conditions
ConditionsYield
With potassium carbonate In water; acetonitrile at 50℃; for 48h; Reagent/catalyst;92%
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2-methoxy-phenol

allyl halide

allyl halide

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O-allyl guaiacol

Conditions
ConditionsYield
With potassium carbonate In acetone70%
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4-iodoanisol

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allyl alcohol

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O-allyl guaiacol

Conditions
ConditionsYield
With caesium carbonate; copper(l) iodide at 110℃; for 22h;55%
With copper(l) iodide; (11R,12R)-9,10-dihydro-9,10-ethanoanthracene-11,12-dimethanol; caesium carbonate at 82℃; for 36h; Ullmann coupling;50%
7575-57-7

allyl benzenesulfonate

13052-77-2

sodium 2-methoxyphenolate

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O-allyl guaiacol

Conditions
ConditionsYield
With ethanol
556-56-9

allyl iodid

90-05-1

2-methoxy-phenol

4125-43-3

O-allyl guaiacol

Conditions
ConditionsYield
With potassium carbonate
90-05-1

2-methoxy-phenol

107-05-1

3-chloroprop-1-ene

4125-43-3

O-allyl guaiacol

Conditions
ConditionsYield
With sodium hydroxide
With potassium carbonate; acetone; sodium iodide
5633-98-7

potassium guaiacolate

106-95-6

allyl bromide

4125-43-3

O-allyl guaiacol

Conditions
ConditionsYield
With methanol; diethyl ether
90-05-1

2-methoxy-phenol

107-18-6

allyl alcohol

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O-allyl guaiacol

Conditions
ConditionsYield
With dicyclohexyl-carbodiimide
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