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CAS No.: | 2580-79-2 | ||
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Name: | DIAMINOGLYOXIME | ||
Article Data: | 35 | ||
Molecular Structure: | |||
Formula: | C2H6 N4 O2 | ||
Molecular Weight: | 118.095 | ||
Synonyms: | Ethanediimidamide,N,N''-dihydroxy- (9CI); Glyoxime, diamino- (6CI,7CI); Oxamidoxime (8CI);Diaminoglyoxime; Ethanediamide, dioxime; Ethanediamidoxime; NSC 70867; Oxamidedioxime | ||
Density: | 1.9g/cm3 | ||
Melting Point: | 200-204 °C | ||
Boiling Point: | 238.1°Cat760mmHg | ||
Flash Point: | 97.8°C | ||
Safety: |
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PSA: | 117.22000 | ||
LogP: | -0.12020 |
Glyoxal
diaminoglyoxime
Conditions | Yield |
---|---|
With hydroxylamine In water at 95℃; | 80% |
With hydroxylamine In water at 95℃; for 96h; | 80% |
With hydroxylamine In water for 72h; Reflux; | 80% |
Conditions | Yield |
---|---|
With sodium hydroxide; hydroxylamine hydrochloride at 90℃; for 6h; | 60% |
With sodium hydroxide; hydroxylamine hydrochloride for 0.05h; microwave irradiation; | 60% |
With hydroxylamine hydrochloride; sodium hydroxide at 90℃; |
3,4-dibromo-1,2,5-oxadiazole 2-oxide
diaminoglyoxime
Conditions | Yield |
---|---|
With ethanol; ammonia at 60 - 100℃; im Einschlussrohr; |
Conditions | Yield |
---|---|
With potassium hydroxide; hydroxylamine hydrochloride; water man filtriert von sich ausscheidenden Krystallen ab und behandelt das Filtrat von neuem mit Dicyan, bis ein amorpher Niederschlag auftritt; | |
With hydroxylamine | |
With sodium hydroxide; hydroxylamine hydrochloride at 0℃; |
Cyan-imidoameisensaeureethylester
diaminoglyoxime
Conditions | Yield |
---|---|
With diethyl ether; hydroxylamine hydrochloride; water unter Kuehlung; |
1,2-Bisethan-1,2-diamin
diaminoglyoxime
Conditions | Yield |
---|---|
With ethanol; hydroxylamine hydrochloride |
Conditions | Yield |
---|---|
With ethanol; hydroxylamine hydrochloride man filtriert nach dem Erkalten vom ausgeschiedenen Oxalsaeurediamidoxim ab, neutralisiert das Filtrat mit Soda und destilliert im Dampfstrome; den Rueckstand verdampft man zur Trockne und extrahiert ihn mit Alkohol; |
N,N''-dibenzyl-oxalamidine
diaminoglyoxime
Conditions | Yield |
---|---|
With ethanol; hydroxylamine hydrochloride |
Conditions | Yield |
---|---|
With ethanol; hydroxylamine hydrochloride; sodium carbonate |
Conditions | Yield |
---|---|
(i) aq. Na2CO3, CH2Cl2, (ii) NH3, EtOH; Multistep reaction; |