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CAS No.: | 2495-37-6 |
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Name: | Benzyl methacrylate |
Article Data: | 41 |
Molecular Structure: | |
Formula: | C11H12O2 |
Molecular Weight: | 176.215 |
Synonyms: | Methacrylicacid, benzyl ester (6CI,7CI,8CI);Acryester BZ;Benzyl 2-methyl-2-propenoate;Benzyl 2-methylacrylate;Benzyl methacrylate;BzMA;Fancryl FA-BZM;Light EsterBZ;NSC 20970;Phenylmethyl 2-methyl-2-propenoate; |
EINECS: | 219-674-4 |
Density: | 1.036 g/cm3 |
Melting Point: | <25 °C |
Boiling Point: | 247.033 °C at 760 mmHg |
Flash Point: | 124.13 °C |
Solubility: | Insoluble in water. |
Appearance: | colourless liquid |
Hazard Symbols: | Xi |
Risk Codes: | 36/37/38 |
Safety: | 26 |
PSA: | 26.30000 |
LogP: | 2.30590 |
Conditions | Yield |
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tetrachlorobis(tetrahydrofuran)hafnium(IV) In benzene for 40h; Heating; | 99% |
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 4h; | 90% |
toluene-4-sulfonic acid In benzene for 15h; Heating; | 85% |
Conditions | Yield |
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With C2H3O3(1-)*C37H78N(1+) In hexane at 90℃; for 2h; Reagent/catalyst; Molecular sieve; | 97% |
With lanthanum (III) nitrate * water; 1,1,1-trioctyl-1-methylphosphonium methylcarbonate In hexane for 10h; Molecular sieve; Reflux; | 80% |
Conditions | Yield |
---|---|
With triethylamine at 0℃; Inert atmosphere; Microwave irradiation; | 96% |
With triethylamine In dichloromethane at 0℃; | 62% |
With triethylamine In dichloromethane at 0℃; Inert atmosphere; | 50% |
(1-Benzyloxy-2-chloro-2-methyl-cyclopropoxy)-trimethyl-silane
benzyl methacrylate
Conditions | Yield |
---|---|
With triethylamine In methanol for 6h; Heating; | 91% |
With triethylamine In methanol for 12h; Heating; Yield given; |
benzyl 3-(dimethylamino)-2-methylpropanoate
benzyl methacrylate
Conditions | Yield |
---|---|
With 2-chloro-4,6-dimethoxy-1 ,3,5-triazine; triethylamine In isopropyl alcohol at 20℃; for 0.25h; Eschenmoser Methylenation; | 90% |
Conditions | Yield |
---|---|
With silver(l) oxide In water; acetonitrile at 100℃; for 24h; | A 89% B n/a |
Conditions | Yield |
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With dmap; caesium carbonate at 50℃; for 24h; Concentration; | 89% |
Conditions | Yield |
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With TBA7[γ-HGeW10O36] In acetonitrile at 39.84℃; for 0.0166667h; | 83% |
benzyl 2-(tripheny l-λ5phosphanylidene)propanoate
benzyl methacrylate
Conditions | Yield |
---|---|
With carbon dioxide; potassium tert-butylate In N,N-dimethyl-formamide at 100℃; under 760.051 Torr; for 12h; | 83% |
1,2-propanediene
carbon monoxide
benzyl alcohol
benzyl methacrylate
Conditions | Yield |
---|---|
dodecacarbonyl-triangulo-triruthenium at 80℃; under 22800 Torr; for 5h; | 73% |