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CAS No.: | 23986-74-5 |
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Name: | germacreneD,1-methyl-5-methylene-8-(1-methylethyl)-1,6-cyclodecadiene |
Article Data: | 8 |
Molecular Structure: | |
Formula: | C15H24 |
Molecular Weight: | 204.356 |
Synonyms: | 1,6-Cyclodecadiene,1-methyl-5-methylene-8-(1-methylethyl)-, [S-(E,E)]-; Germacra-1(10),4(15),5-triene,(-)- (8CI); (-)-Germacrene D; Germacrene D |
Density: | 0.85g/cm3 |
Boiling Point: | 279.7°C at 760 mmHg |
Flash Point: | 111.9°C |
PSA: | 0.00000 |
LogP: | 4.89130 |
Farnesol
germacrene D
Conditions | Yield |
---|---|
With sodium carbonate; magnesium chloride In terpene synthase buffer at 25℃; for 18h; pH=10; Enzymatic reaction; | 91.1% |
Farnesol
B
germacrene D
Conditions | Yield |
---|---|
With sodium acetate; magnesium chloride In terpene synthase buffer at 25℃; for 18h; pH=5; Enzymatic reaction; | A 12.32% B 84.3% |
Farnesol
D
germacrene D
Conditions | Yield |
---|---|
With potassium chloride In terpene synthase buffer at 25℃; for 18h; pH=8; Enzymatic reaction; | A 10.7% B 34.2% C 15% D 19.4% E 10.3% |
Farnesol
E
germacrene D
Conditions | Yield |
---|---|
With potassium chloride In terpene synthase buffer at 37℃; for 18h; pH=8; Enzymatic reaction; | A 5.3% B 7.1% C 22.3% D 13.3% E 22.3% F 12.3% |
farnesyl pyrophosphate
germacrene D
Conditions | Yield |
---|---|
With germacradienol synthase SC9B1.20; 2-hydroxyethanethiol In pentane at 30℃; for 24h; | 1.6 mg |
With (S)-germacrene D synthase; 3-[(3-cholamidopropyl)dimethylammonio]propanesulfonate; glycerol; 2-amino-2-hydroxymethyl-1,3-propanediol; 2-hydroxyethanethiol; magnesium chloride In chloroform-d1; water at 25℃; for 24h; pH=7.5; Enzymatic reaction; | |
With Y406F-GDS-His6 In pentane at 20℃; for 120h; pH=7.5; Kinetics; Enzymatic reaction; |
(2E,6E)-<1,1-2H2>-farnesyl diphosphate
D
germacrene D
Conditions | Yield |
---|---|
With Streptomyces coelicolor germacradienol synthase; Tris-Cl; magnesium chloride In water-d2 at 30℃; Enzymatic reaction; |
farnesyl pyrophosphate
B
(-)-geosmin
C
germacrene D
Conditions | Yield |
---|---|
With Streptomyces coelicolor germacradienol synthase; Tris-Cl; magnesium chloride In water at 30℃; for 4h; Enzymatic reaction; |
farnesyl pyrophosphate
A
4α-hydroxygermacra-1(10),5-diene
B
alloaromadendrene
C
germacrene D
Conditions | Yield |
---|---|
With recombinant (His)8-tagged Medicago truncatula MtTPS5 sesquiterpene synthase Y526F mutant; water; magnesium chloride In pentane at 30℃; for 1.5h; pH=7.5; Mechanism; aq. buffer; Enzymatic reaction; optical yield given as %ee; stereospecific reaction; |
farnesyl pyrophosphate
A
δ-cadinol
C
germacrene D
D
(-)-(1R,4S,5R,6R,7S,10R)-7-isopropyl-4,10-dimethyl-tricyclo[4.4.0.01,5]decane-4-ol
Conditions | Yield |
---|---|
With recombinant (His)8-tagged Medicago truncatula MtTPS5 sesquiterpene synthase; water; magnesium chloride In pentane at 30℃; for 1.5h; pH=7.5; Mechanism; aq. buffer; Enzymatic reaction; optical yield given as %ee; stereospecific reaction; |
3-methyl-2-buten-1-ol
germacrene D
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: Escherichia coli hydroxyethylthiazole kinase; ATP; pyruvate kinase / aq. buffer / 16 h / 20 °C / pH 8 / Enzymatic reaction 2: isopentenyl phosphate kinase from Methanocaldococcus jannaschii; ATP; pyruvate kinase / aq. buffer / 16 h / 20 °C / pH 8 / Enzymatic reaction 3: (2E,6E)-FDP synthase from Geobacillus stearothermophilus; (-)-germacrene D synthase from Solidago canadensis; 1,4-dithio-L-threitol; magnesium chloride / aq. buffer / 16 h / 20 °C / pH 8 / Enzymatic reaction View Scheme |