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CAS No.: | 15022-08-9 | ||||||||||||||
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Name: | DIALLYL CARBONATE | ||||||||||||||
Article Data: | 33 | ||||||||||||||
Molecular Structure: | |||||||||||||||
Formula: | C7H10 O3 | ||||||||||||||
Molecular Weight: | 142.155 | ||||||||||||||
Synonyms: | Carbonicacid, di-2-propenyl ester (9CI); Carbonic acid, diallyl ester (6CI,7CI,8CI);Allyl carbonate; Diallyl carbonate; NSC 19177 | ||||||||||||||
Density: | 0.986g/cm3 | ||||||||||||||
Melting Point: | 25°C | ||||||||||||||
Boiling Point: | 172.3°Cat760mmHg | ||||||||||||||
Flash Point: | 58.9°C | ||||||||||||||
Hazard Symbols: | |||||||||||||||
Risk Codes: | 36/37/38 | ||||||||||||||
Safety: |
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PSA: | 35.53000 | ||||||||||||||
LogP: | 1.51160 |
Conditions | Yield |
---|---|
With 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine In neat (no solvent) at 80℃; under 760.051 Torr; for 16h; Inert atmosphere; Green chemistry; | 95% |
With 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine at 80 - 120℃; for 48h; | 61% |
With potassium carbonate at 70℃; for 6h; | 53% |
With sodium methylate at 60℃; for 1h; Inert atmosphere; | 2 %Chromat. |
Conditions | Yield |
---|---|
With copper (I) iodide; dicyclohexyl-carbodiimide at 64.85℃; under 37503 Torr; for 4h; | A 6% B 93% |
With dicyclohexyl-carbodiimide In toluene at 64.85℃; under 37503 Torr; for 6h; | A n/a B 3.3% |
carbon dioxide
allyl alcohol
O-allyl-N,N'-dicyclohexyl isourea
A
Allyl ether
B
diallylcarbonate
Conditions | Yield |
---|---|
at 64.85℃; under 37503 Torr; for 2h; | A 7% B 91% |
Conditions | Yield |
---|---|
With pyridine In diethyl ether a) 0 deg C, 1 h, b) 25 deg C, 5 h; | 85% |
With pyridine In diethyl ether at 25℃; for 5h; | 67% |
Conditions | Yield |
---|---|
With 2-Cyanopyridine; cerium(IV) oxide at 119.84℃; under 37503.8 Torr; for 48h; Autoclave; | 76% |
With dichloromethane; caesium carbonate In 1-methyl-pyrrolidin-2-one at 100℃; under 760.051 Torr; for 24h; | 58% |
With triphenylphosphine; diethylazodicarboxylate In tetrahydrofuran for 18h; | 40% |
With carbon tetrabromide; tributylphosphine; 2-cyclohexyl-1,1,3,3-tetramethylguanidine In N,N-dimethyl-formamide at 20℃; for 2h; Condensation; | 64.1 % Spectr. |
allyl alcohol
diallylcarbonate
Conditions | Yield |
---|---|
With lanthanum(III) chloride; urea at 180℃; for 6h; Reagent/catalyst; Autoclave; | 60.7% |
potassium hydrogencarbonate
allyl bromide
A
Allyl ether
B
diallylcarbonate
Conditions | Yield |
---|---|
tetrabutyl phosphonium bromide In various solvent(s) at 150℃; Solvent: NMP; | A n/a B 50% |
allyl alcohol
carbonic acid dimethyl ester
A
allyl methyl carbonate
B
diallylcarbonate
Conditions | Yield |
---|---|
Stage #1: allyl alcohol; carbonic acid dimethyl ester at 80℃; Stage #2: With 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine at 80℃; for 1h; | A 50% B n/a |
sodium methylate at 23℃; Inert atmosphere of nitrogen; | |
sodium methylate at 23℃; Inert atmosphere of nitrogen; | |
With sodium aluminate at 20 - 90℃; for 24h; |
(2-oxo-1,3-dioxolan-4-yl)methyl 4-methylbenzenesulfonate
allyl alcohol
A
diallylcarbonate
B
allyl glycidyl carbonate
Conditions | Yield |
---|---|
Stage #1: allyl alcohol With sodium hydride In tetrahydrofuran Stage #2: (2-oxo-1,3-dioxolan-4-yl)methyl 4-methylbenzenesulfonate With tetrabutylammomium bromide In tetrahydrofuran at -70 - 20℃; | A 12% B 47% |
tri-n-propylamine
carbon dioxide
A
diallylcarbonate
B
propyl N,N-di-propylcarbamate
Conditions | Yield |
---|---|
With allyl alcohol; acetylene at 160℃; for 16h; | A 6% B 4% C 21% |