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Basic Information
CAS No.: 1487-18-9
Name: 2-ethenylfuran
Article Data: 55
Molecular Structure:
Molecular Structure of 1487-18-9 (2-ethenylfuran)
Formula: C6H6 O
Molecular Weight: 94.113
Synonyms: Furan,2-vinyl- (6CI,7CI,8CI); 2-Ethenylfuran; 2-Vinylfuran; a-Furylethylene
Density: 0.958g/cm3
Melting Point: -94°C
Boiling Point: 100.3°Cat760mmHg
Flash Point: 5.5°C
PSA: 13.14000
LogP: 1.92260
Synthetic route
2745-17-7

2-furyloxirane

1487-18-9

(furan-2-yl)ethylene

Conditions
ConditionsYield
With thiourea In water at 90℃;98%
539-47-9

3-(fur-2-yl)crotonic acid

1487-18-9

(furan-2-yl)ethylene

Conditions
ConditionsYield
With copper(I) oxide In various solvent(s) at 200℃; for 3h;73%
at 270 - 320℃;
With quinoline; copper(II) sulfate
With Camellia sinensis at 25℃; for 120h; pH=6.4; Decarboxylation;
With propane at 350℃;
98-01-1

furfural

15912-74-0

triphenyl(methyl)phosphonium

1487-18-9

(furan-2-yl)ethylene

Conditions
ConditionsYield
With barium dihydroxide; water In 1,4-dioxane at 70℃; for 0.25h; Product distribution; other aldehydes; var. times and reagents;55%
113348-42-8

1,2-epithio-(2'-furyl)-ethane

1487-18-9

(furan-2-yl)ethylene

Conditions
ConditionsYield
With triphenylphosphine54%
98-01-1

furfural

333-27-7

methyl trifluoromethanesulfonate

1487-18-9

(furan-2-yl)ethylene

Conditions
ConditionsYield
With scandium tris(trifluoromethanesulfonate) In acetonitrile Wittig Olefination; Inert atmosphere; Glovebox; Electrochemical reaction;46%
98-00-0

(2-furyl)methyl alcohol

67-56-1

methanol

1487-18-9

(furan-2-yl)ethylene

Conditions
ConditionsYield
With SAPO-34 at 320 - 520℃; for 3h; Reagent/catalyst; Temperature; Inert atmosphere; Molecular sieve;44%
3208-16-0

2-ethylfuran

A

1487-18-9

(furan-2-yl)ethylene

B

2-bromo-5-ethylfuran

Conditions
ConditionsYield
With bromine In N,N-dimethyl-formamide at 20℃; for 1h; Inert atmosphere;A 9%
B 29%
98-01-1

furfural

2065-66-9

methyl-triphenylphosphonium iodide

1487-18-9

(furan-2-yl)ethylene

Conditions
ConditionsYield
Stage #1: methyl-triphenylphosphonium iodide With n-butyllithium In tetrahydrofuran at -78 - 0℃; for 0.25h; Inert atmosphere;
Stage #2: furfural In tetrahydrofuran at 23℃; Inert atmosphere;
21%
Stage #1: methyl-triphenylphosphonium iodide With n-butyllithium In tetrahydrofuran; hexane at 0℃; for 0.25h; Wittig Olefination; Inert atmosphere;
Stage #2: furfural In tetrahydrofuran; hexane at 0 - 20℃; for 2.25h; Wittig Olefination;
98-01-1

furfural

141-82-2

malonic acid

1487-18-9

(furan-2-yl)ethylene

Conditions
ConditionsYield
With quinoline at 200℃; Erhitzen des Reaktionsgemisches mit Kupfer(II)-sulfat auf 150gradC;
98-01-1

furfural

64-19-7

acetic acid

1487-18-9

(furan-2-yl)ethylene

Conditions
ConditionsYield
With potassium acetate-silica gel at 350℃;
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