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| CAS No.: | 13718-94-0 |
|---|---|
| Name: | PALATINOSE |
| Article Data: | 12 |
| Molecular Structure: | |
|
|
|
| Formula: | C12H22O11 |
| Molecular Weight: | 342.3 |
| Synonyms: | Fructose,6-O-a-D-glucopyranosyl-, D- (7CI,8CI);Palatinose (6CI);Galen IQ;Isomaltulose; |
| EINECS: | 237-282-1 |
| Density: | 1.694 g/cm3 |
| Melting Point: | 125-128 °C |
| Boiling Point: | 784.843 °C at 760 mmHg |
| Flash Point: | 292.547 °C |
| Solubility: | almost transparency |
| Appearance: | White crystals |
| Hazard Symbols: |
 Xn
|
| Risk Codes: | 20/21/22-37/38-41-48 |
| Safety: | 22-24/25-45-36/37/39-26 |
| PSA: | 189.53000 |
| LogP: | -5.39560 |
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- 82993-81-5D-threo-Ritalinic acid hydrochloride
- 47087-37-6Z-D-Glu-OMe
- 73441-42-6METHYL-5-CHLORO-2,2-DIMETHYLVALERATE
- 57-50-1
Sucrose
- 13718-94-0
isomaltulose
| Conditions | Yield |
|---|---|
| With protaminobacter rubrum |
- 13718-94-0
isomaltulose
| Conditions | Yield |
|---|---|
| With ammonium hydroxide |
| Conditions | Yield |
|---|---|
| With sucrose isomerase In aq. phosphate buffer at 30℃; for 0.333333h; pH=6; Kinetics; pH-value; Temperature; Enzymatic reaction; |
| Conditions | Yield |
|---|---|
| With trifluoroethanol; 1,8-diazabicyclo[5.4.0]undec-7-ene In methanol at 60℃; for 16h; Overall yield = 25 %; Overall yield = 90 mg; stereoselective reaction; | A 45% B n/a |
| Conditions | Yield |
|---|---|
| With hydrogen; pyrographite In water |
| Conditions | Yield |
|---|---|
| With hydrogen; nickel In water |
- 13718-94-0
isomaltulose
- 534-73-6
isomaltitol
| Conditions | Yield |
|---|---|
| With hydrogen; ruthenium In water | |
| With hydrogen; ruthenium In water | |
| With hydrogen; ruthenium In water | |
| With hydrogen; ruthenium In water |
- 57-48-7
D-Fructose
- 2280-44-6
D-Glucose
- 57-50-1
Sucrose
- 499-40-1
isomaltose
- 51411-23-5
1-O-α-D-glucopyranosyl-β-D-fructose
- 13718-94-0
isomaltulose
A
- 20942-96-5
α-D-glucopyranosyl-(1->6)-D-gulitol
B
- 20942-99-8
1-O-α-D-glucopyranosyl-D-mannitol
C
- 69-65-8
mannitol
D
- 50-70-4
D-sorbitol
E
- 534-73-6
isomaltitol
| Conditions | Yield |
|---|---|
| With hydrogen; nickel In water at 20 - 130℃; under 22502.3 Torr; Product distribution / selectivity; Autoclave; |
- 57-48-7
D-Fructose
- 2280-44-6
D-Glucose
- 499-40-1
isomaltose
- 51411-23-5
1-O-α-D-glucopyranosyl-β-D-fructose
- 13718-94-0
isomaltulose
A
- 20942-96-5
α-D-glucopyranosyl-(1->6)-D-gulitol
B
- 20942-99-8
1-O-α-D-glucopyranosyl-D-mannitol
C
- 69-65-8
mannitol
D
- 50-70-4
D-sorbitol
E
- 534-73-6
isomaltitol
| Conditions | Yield |
|---|---|
| With hydrogen; nickel In water at 20 - 130℃; under 22502.3 - 97509.8 Torr; Product distribution / selectivity; Autoclave; |
- 13718-94-0
isomaltulose
- 50-99-7
D-glucose
| Conditions | Yield |
|---|---|
| With rat intestinal α-glucosidase at 37℃; for 0.333333h; pH=6.8; aq. phosphate buffer; |
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Specification
The D-Fructose, 6-O-a-D-glucopyranosyl-, with CAS registry number 13718-94-0, belongs to the following product categories: (1)Basic Sugars (Mono & Oligosaccharides); (2)Biochemistry; (3)Disaccharides; (4)Sugars. It has the systematic name of 6-O-alpha-D-glucopyranosyl-D-fructose. And the chemical formula of this chemical is C12H22O11. What's more, its EINECS is 237-282-1. The main use of this chemical is for low sweetness nonnutritive sweeteners.
Physical properties of D-Fructose, 6-O-a-D-glucopyranosyl-: (1)ACD/LogP: -2.85; (2)# of Rule of 5 Violations: 2; (3)ACD/LogD (pH 5.5): -2.85; (4)ACD/LogD (pH 7.4): -2.85; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 11; (10)#H bond donors: 8; (11)#Freely Rotating Bonds: 16; (12)Polar Surface Area: 109.37 Å2; (13)Index of Refraction: 1.623; (14)Molar Refractivity: 71.26 cm3; (15)Molar Volume: 202 cm3; (16)Polarizability: 28.25×10-24cm3; (17)Surface Tension: 105 dyne/cm; (18)Density: 1.69 g/cm3; (19)Flash Point: 292.5 °C; (20)Enthalpy of Vaporization: 130.13 kJ/mol; (21)Boiling Point: 784.8 °C at 760 mmHg; (22)Vapour Pressure: 1.84E-28 mmHg at 25°C.
Uses of D-Fructose, 6-O-a-D-glucopyranosyl-: it can be used to produce 5-hydroxymethyl-furan-2-carbaldehyde. This reaction will need solvent dimethylsulfoxide. The reaction time is 2 hour(s) with reaction temperature of 120 ℃. The yield is about 35.8%.
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When you are using this chemical, please be cautious about it as the following:
The D-Fructose, 6-O-a-D-glucopyranosyl- irritates to eyes, respiratory system and skin. And this chemical is harmful by inhalation, in contact with skin and if swallowed. It has risk of serious damage to the eyes and has danger of serious damage to health by prolonged exposure. So ypu should avoid contact with skin and eyes. When use it, wear suitable protective clothing, gloves and eye/face protection. If contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
You can still convert the following datas into molecular structure:
(1)SMILES: O=C(CO)[C@@H](O)[C@H](O)[C@H](O)CO[C@H]1O[C@@H]([C@@H](O)[C@H](O)[C@H]1O)CO
(2)InChI: InChI=1/C12H22O11/c13-1-4(15)7(17)8(18)5(16)3-22-12-11(21)10(20)9(19)6(2-14)23-12/h5-14,16-21H,1-3H2/t5-,6-,7-,8-,9-,10+,11-,12+/m1/s1
(3)InChIKey: RJPPRBMGVWEZRR-WTZPKTTFBY
(4)Std. InChI: InChI=1S/C12H22O11/c13-1-4(15)7(17)8(18)5(16)3-22-12-11(21)10(20)9(19)6(2-14)23-12/h5-14,16-21H,1-3H2/t5-,6-,7-,8-,9-,10+,11-,12+/m1/s1
(5)Std. InChIKey: RJPPRBMGVWEZRR-WTZPKTTFSA-N