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CAS No.: | 10484-56-7 |
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Name: | 2-BUTOXYNAPHTHALENE |
Article Data: | 17 |
Molecular Structure: | |
Formula: | C14H16 O |
Molecular Weight: | 200.28 |
Synonyms: | 2-Butoxynaphthalene;Butyl b-naphthyl ether; Fragarol; b-Naphthol butyl ether |
Density: | 1.016g/cm3 |
Melting Point: | 35-36℃ |
Boiling Point: | 315.3°Cat760mmHg |
Flash Point: | 123.5°C |
PSA: | 9.23000 |
LogP: | 4.01870 |
Conditions | Yield |
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With potassium hydroxide; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate Ambient temperature; | 98% |
With potassium carbonate In acetonitrile at 125℃; for 1h; Microwave irradiation; | 95% |
Conditions | Yield |
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With bismuth(lll) trifluoromethanesulfonate In water; 1,2-dichloro-ethane at 110℃; for 24h; Schlenk technique; Inert atmosphere; | 98% |
2-(but-3-en-1-yloxy)naphthalene
2-butoxynaphthalene
Conditions | Yield |
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With iron(III) chloride; lithium aluminium tetrahydride; hydrogen In tetrahydrofuran at 18℃; under 750.075 Torr; for 20h; Inert atmosphere; Sealed tube; | 65% |
Conditions | Yield |
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With Nafion NR50 at 115℃; for 35h; Inert atmosphere; Large scale reaction; | 97% |
With sulfuric acid |
Conditions | Yield |
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With potassium carbonate In N,N-dimethyl-formamide at 80℃; |
Conditions | Yield |
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With 2,6-dimethylpyridine; tetrabutyl-ammonium chloride; potassium carbonate In water for 8h; Heating; | 97% |
Conditions | Yield |
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With potassium carbonate at 150 - 160℃; for 6h; | 27% |
β-naphthol
2-butoxynaphthalene
Conditions | Yield |
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Multi-step reaction with 2 steps 1: triphenylphosphine; di-isopropyl azodicarboxylate / tetrahydrofuran / 18 h / 20 °C / Inert atmosphere; Cooling with ice 2: hydrogen; iron(III) chloride; lithium aluminium tetrahydride / tetrahydrofuran / 20 h / 18 °C / 750.08 Torr / Inert atmosphere; Sealed tube View Scheme |
Conditions | Yield |
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With ethanol |
Conditions | Yield |
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With sodium hydroxide 1.) EtOH; 2.) THF, 65 deg C; Multistep reaction; |