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CAS No.: | 103-01-5 |
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Name: | Anilinoacetic acid |
Article Data: | 101 |
Molecular Structure: | |
Formula: | C8H9NO2 |
Molecular Weight: | 151.165 |
Synonyms: | H-DL-Phg-OH;TR-NPG;(Phenylamino)aceticacid;Acetic acid, (phenylamino)-;Anilinoacetic acid;N-(Phenylamino)aceticacid;N-Phenylglycine;NSC 83567; |
EINECS: | 203-070-2 |
Density: | 1.259 g/cm3 |
Melting Point: | 121-127 °C |
Boiling Point: | 359 °C at 760 mmHg |
Flash Point: | 170.9 °C |
Solubility: | moderately soluble in water |
Appearance: | ochre to yellow-brown fine powder |
Risk Codes: | 36/37/38 |
Safety: | 22-24/25 |
PSA: | 49.33000 |
LogP: | 1.25610 |
Conditions | Yield |
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Stage #1: ethyl bromoacetate; aniline With silica gel at 20℃; for 0.116667h; microwave irradiation; Stage #2: With sodium hydroxide In ethanol for 0.166667h; Heating; | 93% |
Stage #1: ethyl bromoacetate; aniline With potassium carbonate for 1.5h; Milling; Stage #2: With potassium hydroxide for 1.5h; Milling; | 91% |
Stage #1: ethyl bromoacetate; aniline Stage #2: With sodium hydroxide |
Conditions | Yield |
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90% |
tert-butyl 2-(phenylamino)acetate
N-Phenylglycine
Conditions | Yield |
---|---|
With trifluoroacetic acid In dichloromethane for 3h; | 90% |
In water; isopropyl alcohol at 200℃; for 0.25h; Solvent; Temperature; Flow reactor; | 77% |
Conditions | Yield |
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With potassium phosphate; copper(l) iodide; 2-(N,N-dimethylamino)ethanol In water at 75 - 80℃; for 72h; | 87% |
With copper(l) iodide; 2-(2-methyl-1-oxopropyl)cyclohexanone; caesium carbonate In N,N-dimethyl-formamide at 20℃; for 4h; Inert atmosphere; | 82% |
With copper(I) oxide; caesium carbonate at 100℃; for 0.666667h; Sealed tube; Microwave irradiation; | 10% |
Conditions | Yield |
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With copper(l) iodide; 2-(2-methyl-1-oxopropyl)cyclohexanone; potassium carbonate In water at 90℃; for 0.833333h; Microwave irradiation; Green chemistry; | 81% |
With pectin-stabilized copper nanoparticles In dimethyl sulfoxide at 110℃; for 2h; | 71% |
With potassium phosphate; copper(l) iodide; 2-(N,N-dimethylamino)ethanol In water at 90℃; | 62% |
With copper(l) iodide; potassium carbonate In N,N-dimethyl acetamide at 90℃; |
Conditions | Yield |
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With sodium hydroxide In water for 0.5h; Heating; | 73% |
With sodium hydroxide for 0.5h; Heating; | 70% |
Stage #1: N-phenylglycine ethyl ester With sodium hydroxide In water for 0.5h; Reflux; Stage #2: With hydrogenchloride In water pH=2; |
1-phenyl-4-oximinoimidazolidine
N-Phenylglycine
Conditions | Yield |
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With hydrogenchloride Hydrolysis; | 60% |
iodobenzene
glycylglycine
A
N-(N-phenyl-glycyl)-glycine
B
N-Phenylglycine
Conditions | Yield |
---|---|
With potassium phosphate; copper(l) iodide; 2-(N,N-dimethylamino)ethanol In water at 70℃; for 16h; | A 40% B 27% |
Conditions | Yield |
---|---|
With sulfuric acid Electrolysis.elektrolytische Reduktion; |
Conditions | Yield |
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With potassium cyanide; ethanol |