glyoxime-N_.N'-diphenyl ether

Base Information

• Chemical Name: glyoxime-N_.N'-diphenyl ether
• CAS No.: 13532-81-5
• Molecular Formula: C₁₄H₁₂N₂O₂
• Molecular Weight: 240.261
• Mol file: 13532-81-5.mol

Synonyms:glyoxime-N_.N'-diphenyl ether

Chemical Property of glyoxime-N_.N'-diphenyl ether

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of glyoxime-N_.N'-diphenyl ether

There total 30 articles about glyoxime-N_.N'-diphenyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

N-ethylidenecyclohexylamine (113832-57-8,1193-93-7) → glyoxime-N.N'-diphenyl ether (13532-81-5) + N,N'-dicyclohexylethylenediimine (3673-06-1) + azoxybenzene (495-48-7,55599-32-1)

Guidance literature:

With Nitrosobenzene; In benzene; for 5h; Ambient temperature;

Reference yield: 90.0%

N-ethylidenecyclohexylamine (113832-57-8,1193-93-7) + Nitrosobenzene (586-96-9) → glyoxime-N.N'-diphenyl ether (13532-81-5) + N,N'-dicyclohexylethylenediimine (3673-06-1) + azoxybenzene (495-48-7,55599-32-1)

Guidance literature:

In benzene; for 5h; Ambient temperature;

Reference yield: 83.0%

N-ethylidene-N-isopropyl amine (27719-14-8) + Nitrosobenzene (586-96-9) → 1,4-diisopropyl-1,4-diazabuta-1,3-diene (28227-41-0,24764-90-7) + glyoxime-N.N'-diphenyl ether (13532-81-5) + azoxybenzene (495-48-7,55599-32-1)

Guidance literature:

In diethyl ether; for 12h; Ambient temperature;

upstream raw materials:

diazomethane

diethyl ether

Nitrosobenzene

1-(N-hydroxy-anilinomethyl)-piperidine

Downstream raw materials:

Glyoxal

N-Phenylhydroxylamine

Nitrosobenzene

aniline

Refernces

• 1、 Chakraborty, Bhaskar,Luitel, Govinda Prasad. "Synthesis of some novel bisisoxazolidine derivatives from glyoxal-derived bisnitrones via simultaneous double cycloaddition reactions in water". supporting information. p. 726 - 731. Retrieved 2015/05/13.
• 2、 Murray, Robert W.,Singh, Megh. "A Facile One-Step Synthesis of C-Arylnitrones Using Dimethyldioxirane". . p. 2954 - 2957. Retrieved 2007/10/02.