27719-14-8

Basic information

• Product Name: N-[(1E)-ethylidene]propan-2-amine
• Synonyms: 2-Propanamine, N-ethylidene-
• CAS NO: 27719-14-8
• Molecular Formula: C₅H₁₁N
• Molecular Weight: 85.1475
• Mol File: 27719-14-8.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 102.4°C at 760 mmHg
• Flash Point: 6.6°C
• Density: 0.74g/cm³
• Vapor Pressure: 38.9mmHg at 25°C
• Refractive Index: 1.405
• PKA: 6.86±0.50(Predicted)
• CAS DataBase Reference: N-[(1E)-ethylidene]propan-2-amine(CAS DataBase Reference)
• NIST Chemistry Reference: N-[(1E)-ethylidene]propan-2-amine(27719-14-8)
• EPA Substance Registry System: N-[(1E)-ethylidene]propan-2-amine(27719-14-8)

Safety Data

• Hazardous Substances Data: 27719-14-8(Hazardous Substances Data)

Upstream product

• 75-07-0 acetaldehyde 
• 75-31-0 isopropylamine 
• 75-05-8 acetonitrile 
• 75-29-6 isopropyl chloride 
• 13304-31-9 Tetra-isopropyl-2-tetrazen 
• 13304-31-9 1,1,4,4-Tetraisopropyl-2-tetrazen 

Downstream Products

• 19961-27-4 N-isopropylethylamine 
• 19302-16-0 N-isopropyl-(+/-)-α-methylbenzylamine 
• 113445-16-2 (E)-3-Isopropylamino-1-(1-methyl-cyclohexa-2,5-dienyl)-propenone 
• 81264-58-6 1-(N-Nitroso-N-isopropylamino)ethyl acetate 
• 92667-39-5 N-<1-(4-Nitrobenzoyloxy)ethyl>-N-nitrosoisopropylamin 
• 113445-31-1 (E)-1-(1,3-Dimethyl-cyclohexa-2,5-dienyl)-3-isopropylamino-propenone 
• 113445-32-2 (E)-3-Isopropylamino-1-(3-methoxy-1-methyl-cyclohexa-2,5-dienyl)-propenone 
• 28227-41-0 1,4-diisopropyl-1,4-diazabuta-1,3-diene 
• 13532-81-5 glyoxime-N_.N'-diphenyl ether 
• 495-48-7 azoxybenzene 
• 27719-15-9 N-vinyl-N-isopropylcarbamyl chloride 
• 554-68-7 triethylamine hydrochloride 
• 95554-65-7 (+/-)-5-Benzyloxy-3-(1-isopropylamino-ethyl)-indol 
• 81363-76-0 propane-2-sulfonamide 

Relevant articles and documents

CONFIGURATION AND CONFORMATION OF LITHIATED IMINES BY DNMR STUDIES AND AB INITIO CALCULATIONS

The N-isopropyl imine of lithioacetaldehyde, I, was found to exist as a 50:50 mixture of two isomers, as seen below -20 deg C by 1H and 13C NMR.Comparison of the population ratio and spectral characteristics of the isomers of this and related lithiated im

CHOLECYSTOKININ ANTAGONISTS, THEIR PREPARATION AND THERAPEUTIC USE

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Electronic Structure and Gas-Phase Thermolysis of 2-Tetrazenes with Acyclic or Cyclic Amino Groups Studied by Photoelectron Spectroscopy

The electronic structures and the gas-phase thermolysis of the 2-tetrazenes 2-13 have been studied by He(I) photoelectron spectroscopy.The compounds are characterized by at least three ionization potentials with energies less than 10 eV which are assigned to the molecular orbitals ?3 (HOMO), n(+), ?2, and n(-).In the thermolyses either the formal disproportionation products (amine and imine) of the respective aminyl radical are found, or the latter is stabilized by loss of an alkyl radical affording also an imine.Further products which can be explained by radical reactions are detected in flash vacuum pyrolyses.The tricyclic cis-2-tetrazene 13 is cleaved by cycloreversion.The methoxymethylsubstituted compound 8 exhibit a more complex cleavage pattern. - Key Words: Electronic structure / PE spectroscopy / Thermolysis, gas-phase / Imines / Radicals