nickel(II) 5,10,15,20-tetrakis(4-aminophenyl)-21H,23H-porphine

Base Information

• Chemical Name: nickel(II) 5,10,15,20-tetrakis(4-aminophenyl)-21H,23H-porphine
• CAS No.: 67595-99-7
• Molecular Formula: C₄₄H₃₂N₈Ni
• Molecular Weight: 731.482
• Mol file: 67595-99-7.mol

Synonyms:nickel(II) 5,10,15,20-tetrakis(4-aminophenyl)-21H,23H-porphine

Chemical Property of nickel(II) 5,10,15,20-tetrakis(4-aminophenyl)-21H,23H-porphine

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of nickel(II) 5,10,15,20-tetrakis(4-aminophenyl)-21H,23H-porphine

There total 8 articles about nickel(II) 5,10,15,20-tetrakis(4-aminophenyl)-21H,23H-porphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

tetrakis(4-aminophenyl)porphyrin (22112-84-1) + nickel(II) acetate tetrahydrate (6018-89-9) → 5,10,15,20-tetrakis(para-aminophenyl)porphyrin nickel(II) (67595-99-7)

Guidance literature:

In dichloromethane; N,N-dimethyl-formamide; Reflux;

DOI:10.1002/cctc.202001876

Reference yield: 85.0%

nickel(II) chloride hexahydrate + tetrakis(4-aminophenyl)porphyrin (22112-84-1) → 5,10,15,20-tetrakis(para-aminophenyl)porphyrin nickel(II) (67595-99-7)

Guidance literature:

In methanol; chloroform; N,N-dimethyl-formamide; for 24h; Reflux; Inert atmosphere;

DOI:10.1039/d1cc04928c

Reference yield: 74.0%

tetrakis(4-aminophenyl)porphyrin (22112-84-1) → nickel(II) 5,10,15,20-tetrakis(4-aminophenyl)-21H,23H-porphine (67595-99-7)

Guidance literature:

With nickel(II) acetate tetrahydrate; In methanol; chloroform; N,N-dimethyl-formamide; for 24h; Reflux;

DOI:10.1002/anie.201100193

upstream raw materials:

nickel dichloride

tetrakis(4-aminophenyl)porphyrin

nickel(II) acetate tetrahydrate

4-nitrobenzaldehdye

Refernces

• 1、 Meng, Jing,Xu, Ze,Li, Hongxi,James Young, David,Hu, Chuanjiang,Yang, Yonggang. "Porphyrin-based NiFe Porous Organic Polymer Catalysts for the Oxygen Evolution Reaction". . p. 1396 - 1402. Retrieved 2021/02/03.
• 2、 Liu, Chang,Li, Hao,Liu, Fei,Chen, Junsheng,Yu, Zixun,Yuan, Ziwen,Wang, Chaojun,Zheng, Huiling,Henkelman, Graeme,Wei, Li,Chen, Yuan. "Intrinsic Activity of Metal Centers in Metal-Nitrogen-Carbon Single-Atom Catalysts for Hydrogen Peroxide Synthesis". . p. 21861 - 21871. Retrieved 2021/01/11.