2-Iodo-9H-fluorene

Base Information

• Chemical Name: 2-Iodo-9H-fluorene
• CAS No.: 2523-42-4
• Molecular Formula: C13H9 I
• Molecular Weight: 292.119
• Hs Code.: 29039990
• European Community (EC) Number: 627-435-4
• NSC Number: 12354
• DSSTox Substance ID: DTXSID40279334
• Nikkaji Number: J308.128A
• Wikidata: Q72483623
• Mol file: 2523-42-4.mol

Synonyms:2-Iodo-9H-fluorene;2-Iodofluorene;2523-42-4;9H-Fluorene, 2-iodo-;2-iodo-fluorene;C13H9I;NSC 12354;MFCD00019049;NSC12354;2-iodo-9H- fluorene;2-Iodofluorene, 98%;Maybridge1_002237;SCHEMBL481172;HMS547N15;VNYQUOAQPXGXQO-UHFFFAOYSA-;DTXSID40279334;2-iodo-9H-fluorene;NSC-12354;AKOS001061208;AM84836;FD14026;SB66934;AC-24444;AS-48895;SY036407;CS-0020123;FT-0612657;I0793;EN300-17399;A817725;Z56926512

Chemical Property of 2-Iodo-9H-fluorene

Chemical Property:

• Vapor Pressure: 1.66E-05mmHg at 25°C
• Melting Point: 126-129 °C
• Boiling Point: 375.6°Cat760mmHg
• Flash Point: 170.6°C
• PSA: 0.00000
• Density: 1.714g/cm³
• LogP: 3.86240
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 291.97490
• Heavy Atom Count: 14
• Complexity: 213

Purity/Quality:

99% ^*data from raw suppliers

2-Iodo-9H-fluorene ^*data from reagent suppliers

Safty Information:

• Hazard Codes: N,Xi
• Statements: 51/53
• Safety Statements: 61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1C2=CC=CC=C2C3=C1C=C(C=C3)I

Technology Process of 2-Iodo-9H-fluorene

There total 14 articles about 2-Iodo-9H-fluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

9H-fluorene-2-diazonium tetrafluoroborate → 2-iodo-9H-fluorene (2523-42-4)

Guidance literature:

With trimethylsilyl iodide; methyl iodide; In N,N-dimethyl-formamide; for 1h; Ambient temperature;

DOI:10.1246/bcsj.62.89

Reference yield: 94.0%

9H-fluorene (86-73-7) → 2-iodo-9H-fluorene (2523-42-4)

Guidance literature:

With N,N,N-trimethylbenzenemethanaminium dichloroiodate; zinc(II) chloride; In acetic acid; for 3h; Ambient temperature;

DOI:10.1246/bcsj.62.439

Reference yield: 74.0%

2-aminofluorene (153-78-6) → 2-iodo-9H-fluorene (2523-42-4)

Guidance literature:

With hydrogenchloride; potassium iodide; sodium nitrite; In water; at 5 ℃;

DOI:10.1021/ol500696p

upstream raw materials:

9H-fluorene

(9H-fluoren-2-yl)hydrazine hydrochloride

2-aminofluorene

3-fluoro-4-bromophenylamine

Downstream raw materials:

C₂₆H₁₈Te

9H-fluorene

2-methyl-9H-fluorene

2-iodofluorenone

Refernces

• 1、 Belfield, Kevin D.,Channar, Pervaiz Ali,Irfan, Madiha,Mahar, Jamaluddin,Saeed, Aamer,Shabir, Ghulam,Ul-Hamid, Anwar. "Donor-Pi-Acceptor Fluorene Conjugates, Based on Chalcone and Pyrimidine Derivatives: an Insight into Structure-Property Relationship, Photophysical and Electrochemical Properties". . . Retrieved 2020.
• 2、 Zhang, Yu-Mo,Wang, Xiaojun,Li, Wen,Zhang, Weiran,Li, Minjie,Zhang, Sean Xiao-An. "Bio-inspired enol-degradation for multipurpose oxygen sensing". . p. 13477 - 13480. Retrieved 2014.
• 3、 Kurpanik, Aneta,Matussek, Marek,Szafraniec-Gorol, Gra?yna,Filapek, Micha?,Lodowski, Piotr,Marcol-Szumilas, Beata,Ignasiak, Witold,Ma?ecki, Jan Grzegorz,Machura, Barbara,Ma?ecka, Magdalena,Danikiewicz, Witold,Pawlus, Sebastian,Krompiec, Stanis?aw. "APEX Strategy Represented by Diels–Alder Cycloadditions—New Opportunities for the Syntheses of Functionalised PAHs". supporting information. p. 12150 - 12157. Retrieved 2020/09/01.