Sodium trithiocarbonate

Base Information

• Chemical Name: Sodium trithiocarbonate
• CAS No.: 534-18-9
• Deprecated CAS: 128324-20-9
• Molecular Formula: CH2 S3 . 2 Na
• Molecular Weight: 154.189
• European Community (EC) Number: 208-592-4
• UNII: Y01PT1AS4O
• DSSTox Substance ID: DTXSID7060203
• Nikkaji Number: J188.377A
• Wikidata: Q27294086
• ChEMBL ID: CHEMBL471245
• Mol file: 534-18-9.mol

Synonyms:Sodium trithiocarbonate;Carbonotrithioic acid, disodium salt;534-18-9;disodium;carbonotrithioate;Y01PT1AS4O;disodium carbonotrithioate;CHEMBL471245;Sodium sulfocarbonate;UNII-Y01PT1AS4O;Trithiocarbonic acid disodium salt;EINECS 208-592-4;AQUAMET T;Sodium Carbonotrithioate;disodium trithiocarbonate;TRAMFLOC 904;DISODIUM THIOCARBONATE;SCHEMBL1492384;DTXSID7060203;USAIOOFEIMNEDN-UHFFFAOYSA-L;SODIUM TRITHIOCARBONATE [MI];AKOS006229270;Carbonotrithioic acid, sodium salt (1:2);CARBONOTRITHIOIC ACID SODIUM SALT (1:2);Q27294086

Chemical Property of Sodium trithiocarbonate

Chemical Property:

• Boiling Point: 57.8°Cat760mmHg
• Flash Point: °C
• PSA: 82.69000
• Density: g/cm³
• LogP: 1.66630
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 153.89575208
• Heavy Atom Count: 6
• Complexity: 18.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

SODIUM THIOCARBONATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=S)([S-])[S-].[Na+].[Na+]
• Uses: Usually supplied as a 40°Bé solution for destroying insects injurious to plants, especially vines.

Technology Process of Sodium trithiocarbonate

There total 20 articles about Sodium trithiocarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

carbon disulfide (75-15-0,12122-00-8) → sodium trithiocarbonate (534-18-9)

Guidance literature:

With hydrogen sulfide; sodium isopropylate; In isopropyl alcohol; at 3 ℃; Heating;

Reference yield: 56.0%

carbon disulfide (75-15-0,12122-00-8) + sodium hydroxide (1310-73-2) → sodium trithiocarbonate (534-18-9)

Guidance literature:

In not given; shaking at 14-17°C, 85 h, with 15% soln. of NaOH;

Reference yield:

carbon disulfide (75-15-0,12122-00-8) → disodium 1,3-dithiol-2-thione-4,5-dithiolate (54995-24-3) + sodium trithiocarbonate (534-18-9)

Guidance literature:

With sodium; In N,N-dimethyl-formamide; at 0 - 20 ℃;

DOI:10.1021/ol300477b

upstream raw materials:

carbon disulfide

trithiocarbonic acid

sodium ethanolate

acetone

Downstream raw materials:

cis+trans-dibromoethylene

1,3-dithiolane-2-thione

1-methyl-2-pyridinethione

1,3-di(isobutyl)thiourea

Refernces

• 1、 -. "Blue light absorbing compound". Paragraph 0160. . Retrieved 2019/01/04.
• 2、 Roy, Anne-Lise,Bui, Chong,Rau, Ileana,Kajzar, Fran?ois,Charleux, Bernadette,Save, Maud,Kreher, David,Attias, André-Jean. "Well-defined second-order nonlinear optical polymers by controlled radical polymerization, via multifunctional macromolecular chain transfer agent: Design, synthesis, and characterizations". . p. 782 - 787. Retrieved 2014/02/14.