Methoxypropene

Base Information

• Chemical Name: Methoxypropene
• CAS No.: 7319-16-6
• Molecular Formula: C4H8O
• Molecular Weight: 72.1069
• DSSTox Substance ID: DTXSID301319037
• Mol file: 7319-16-6.mol

Synonyms:methoxypropene;Ether, methyl propenyl, (Z)-;1-Methoxy-propene;methyl (1-propenyl) ether;DTXSID301319037;FT-0628372

Chemical Property of Methoxypropene

Chemical Property:

• Refractive Index: 1.389
• Boiling Point: 36.4 °C at 760 mmHg
• PSA: 9.23000
• Density: 0.762 g/cm³
• LogP: 1.16640
• XLogP3: 1.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 72.057514874
• Heavy Atom Count: 5
• Complexity: 30.6

Purity/Quality:

98% ^*data from raw suppliers

METHYL 1-PROPENYL ETHER 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC=COC

Technology Process of Methoxypropene

There total 1 articles about Methoxypropene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Methyl-prop-(E)-ylidene-oxonium → methanol (67-56-1) + methyl prop-1-enyl ether (7319-16-6) + propylideneamine; protonated form + propionaldehyde (123-38-6)

Guidance literature:

With ammonia; Kinetics;

DOI:10.1039/b209955c

Reference yield: 83.6%

methyl prop-1-enyl ether (7319-16-6) + 1,1,4,4-tetramethoxy-2-butene (5370-08-1) → (2E,4E,6E)-2,7-dimethyl-2,4,6-octatrienedial (5056-17-7)

Guidance literature:

methyl prop-1-enyl ether; 1,1,4,4-tetramethoxy-2-butene; With iron(III) chloride; In toluene; at 25 ℃; for 6h;

With sulfuric acid; water; In toluene; at 80 ℃; for 5 - 8h;

With water; sodium hydrogencarbonate; In toluene; at 80 - 85 ℃; for 3 - 4h; Product distribution / selectivity;

Reference yield: 79.0%

methyl prop-1-enyl ether (7319-16-6) + N-(4-methylphenyl)trifluoroacetohydrazonoyl bromide (98664-40-5) → 4-methyl-1-tolyl-3-trifluoromethyl-1H-pyrazole

Guidance literature:

With triethylamine; In tetrahydrofuran; at 20 ℃; for 24h; regioselective reaction; Inert atmosphere;

DOI:10.1039/c7ob03126b

Downstream raw materials:

3-methoxy-2,6-dimethyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-octa-4t,6t-dienal-dimethylacetal

methyl N-( p-toluenesulfonyl)propionimidate

4-methyl-5-methoxy-2-(4-chlorophenyl)-2-oxazoline

1-Chloro-4-(2-chloro-2-methoxy-1-methyl-ethylsulfanyl)-benzene

Refernces