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Cas Database

Name	Iodomethyl pivalate	EINECS	258-339-7
CAS No.	53064-79-2	Density	1.614 g/cm³
PSA	26.30000	LogP	1.96820
Solubility	N/A	Melting Point	33-35 °C(lit.)
Formula	C₆H₁₁IO₂	Boiling Point	197.2 °C at 760 mmHg
Molecular Weight	242.057	Flash Point	73.1 °C
Transport Information	N/A	Appearance	Sight yellow or colorless
Safety		Risk Codes	N/A
Molecular Structure		Hazard Symbols	N/A
Synonyms	IodomethylPivalate;LDO17:Iodomethyl Pivalate;iodomethyl 2,2-dimethylpropanoate;	Article Data	60

Iodomethyl pivalate Synthetic route

: 18997-19-8
Chloromethyl pivalate

: 53064-79-2
iodomethyl pivaloate

Conditions

Conditions	Yield
With sodium iodide; calcium chloride In ethyl acetate at 78℃; for 6h;	94%
With sodium iodide In acetonitrile at 30℃; for 5h; Inert atmosphere;	86.6%
With sodium iodide In acetonitrile at 30℃; Inert atmosphere;	85%

: 66542-51-6
chloromethyl hexanoate

A: 63379-66-8
iodomethyl hexanoate

B: 53064-79-2
iodomethyl pivaloate

Conditions

Conditions	Yield
With sodium iodide In acetone	A 78% B n/a

Sodium iodide (dried): Sodium iodide (dried)

: 18997-19-8
Chloromethyl pivalate

: 53064-79-2
iodomethyl pivaloate

Conditions

Conditions	Yield
In acetonitrile	75%

: 188680-60-6
trioxane

: 3282-30-2
pivaloyl chloride

: 53064-79-2
iodomethyl pivaloate

Conditions

Conditions	Yield
With sodium iodide In hexane; water; acetonitrile	66%

: 18997-19-8
Chloromethyl pivalate

: 75-36-5
acetyl chloride

: 53064-79-2
iodomethyl pivaloate

Conditions

Conditions	Yield
With sodium iodide In acetone

: C18H18O4

: 53064-79-2
iodomethyl pivaloate

: C24H28O6

Conditions

Conditions	Yield
With N-ethyl-N,N-diisopropylamine	100%

: 1147849-04-4
(6R,7S,Z)-7-(2-(5-amino-1,2,4-thiadiazol-3-yl)-2-(trityloxyimino)acetamido)-8-oxo-3-(trifluoromethylsulfonyloxy)-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid

: 53064-79-2
iodomethyl pivaloate

: 1147849-85-1
(6R,7S,Z)-pivaloyloxymethyl 7-(2-(5-amino-1,2,4-thiadiazol-3-yl)-2-(trityloxyimino)acetamido)-8-oxo-3-(trifluoromethylsulfonyloxy)-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide; triethylamine In N,N-dimethyl-formamide at 0℃; for 0.833333h;	100%

: 6626-84-2
dimethyl 2-benzylidenepropanedioate

: 53064-79-2
iodomethyl pivaloate

: 1383105-29-0
dimethyl 2-hydroxymethyl-2-(1-phenyl-2-pivaloyloxyethyl)malonate

Conditions

Conditions	Yield
With tert.-butylhydroperoxide; boron trifluoride diethyl etherate; dimethyl zinc(II) In decane; hexane; dichloromethane at 20℃; for 3h; Cooling with ice;	99%

: 53064-79-2
iodomethyl pivaloate

: 52927-44-3
dimethyl 2-(4-chlorobenzylidene)malonate

: 1383105-33-6
dimethyl 2-(1-(4-chlorophenyl)-2-pivaloyloxyethyl)-2-hydroxymethylmalonate

Conditions

Conditions	Yield
With tert.-butylhydroperoxide; boron trifluoride diethyl etherate; dimethyl zinc(II) In decane; hexane; dichloromethane at 20℃; for 4h; Cooling with ice;	99%

: 53064-79-2
iodomethyl pivaloate

: 7443-25-6
dimethyl 2-(4-methoxybenzylidene)malonate

: 1383105-35-8
dimethyl 2-hydroxymethyl-2-(1-(4-methoxyphenyl)-2-pivaloyloxyethyl)malonate

Conditions

Conditions	Yield
With tert.-butylhydroperoxide; boron trifluoride diethyl etherate; dimethyl zinc(II) In decane; hexane; dichloromethane at 20℃; for 4h; Cooling with ice;	99%

Iodomethyl pivalate Chemical Properties

IUPAC Name:Iodomethyl 2,2-dimethylpropanoate
Molecular Formula:C₆H₁₁IO₂
Formula Weight:242.05481g/mol
Melting Point:33-35°C
Boiling Point:211.5°C
EINECS:210-841-7
Index of Refraction:1.506
Molar Refractivity:44.55 cm³
Molar Volume:149.9 cm³Polarizability:17.66 ×10^-24cm³
Surface Tension:34.9 dyne/cm
Density:1.614 g/cm³
Flash Point:73.1 °C
Enthalpy of Vaporization:43.34 kJ/mol
Vapour Pressure:0.383 mmHg at 25°C
Covalently-Bonded Unit Count:1
Synonyms of Iodomethyl pivalate (53064-79-2): Auroraka-7367 ; Iodotoluene(4-) ; Iodomethyl pivalate
Product Categories of Iodomethyl pivalate (53064-79-2):Miscellaneous
Structure of Iodomethyl pivalate (53064-79-2):

Iodomethyl pivalate Uses

It can be used as pharmaceutical intermediates and biochemical reagents.

Iodomethyl pivalate Safety Profile

WGK Germany is 3.

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