Catalysis Science & Technology
Communication
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Conclusions
In conclusion, we report a noteworthy feature of a dealloyed
np-Pd catalyst for one-pot cross-coupling reaction of aryl
iodides with organosilanes. Based on the experimental obser-
vations of np-Pd's activity in catalyzing organosilane oxida-
tion with ROH (water or alcohols) and silicon-based cross-
coupling reaction, we realized a one-pot synthesis from aryl
iodides and organosilanes to produce directly the aryl–aryl
coupling products in excellent yield. The results described
here not only represent the first report of dealloyed nano-
porous metals used in one-pot reaction but are also helpful
to promote the development of new sustainable processes for
clean and efficient one-pot green synthesis.
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Acknowledgements
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Financial support from the National 973 (2012CB932800) Pro-
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