Silane, methoxydimethylphenyl-

Base Information

• Chemical Name: Silane, methoxydimethylphenyl-
• CAS No.: 17881-88-8
• Molecular Formula: C9H14OSi
• Molecular Weight: 166.295
• Hs Code.: 29319090
• Mol file: 17881-88-8.mol

Synonyms:Silane,methoxydimethylphenyl- (6CI,8CI,9CI);Methoxy(phenyl)dimethylsilane;Methoxydimethylphenylsilane;Phenyldimethylmethoxysilane;

Chemical Property of Silane, methoxydimethylphenyl-

Chemical Property:

• Vapor Pressure: 0.858mmHg at 25°C
• Refractive Index: 1.475
• Boiling Point: 187.7 °C at 760 mmHg
• Flash Point: 58.8 ºC
• PSA: 9.23000
• Density: 0.91 g/cm³
• LogP: 1.74510
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive.: Moisture Sensitive

Purity/Quality:

99% ^*data from raw suppliers

DiMethylMethoxyphenylsilane ^*data from reagent suppliers

Safty Information:

• Statements: 36/38
• Safety Statements: 26-37

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Silane, methoxydimethylphenyl-

There total 34 articles about Silane, methoxydimethylphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

methanol (67-56-1) + Dimethylphenylsilane (766-77-8) + nitrobenzene (98-95-3,26969-40-4) → methoxydimethylphenylsilane (17881-88-8) + aniline (62-53-3)

Guidance literature:

With palladium; at 20 ℃; for 1h; under 760.051 Torr;

DOI:10.1016/j.inoche.2018.12.004

Reference yield: 79.0%

chloromethyldimethylphenylsilane (1833-51-8) + sodium methylate (124-41-4) → dimethyldimethoxysilan (1112-39-6) + methoxydimethylphenylsilane (17881-88-8) + methoxy(dimethylphenylsilyl)methane (17876-91-4)

Guidance literature:

In methanol; at 65 ℃; for 12h; Product distribution; variation of reactants, solvents, temperature and reaction time;

DOI:10.1016/S0040-4039(00)98410-7

Reference yield: 54.0%

dimethylphenyl(trimethylgermyl)silane (37865-47-7) → methoxydimethylphenylsilane (17881-88-8) + Dimethyldiphenylsilane (778-24-5)

Guidance literature:

With methanol; In cyclohexane; for 1h; Ambient temperature; Irradiation;

DOI:10.1016/0022-328X(91)86036-P

upstream raw materials:

methanol

Dimethylphenylsilane

1-Ethynyl-1,1,2,2-tetramethyl-2-phenyl-disilane

dimethylphenyl(trimethylgermyl)silane

Downstream raw materials:

fluorodimethylphenylsilane

methanol

dimethylphenylsilanol

(E)-benzalacetone

Refernces

• 1、 Leigh, William J.,Sluggett, Gregory W.. "Aryldisilane photochemistry. A kinetic and product study of the mechanism of alcohol additions to transient silenes". . p. 10468 - 10476. Retrieved 1994.
• 2、 Dhakshinamoorthy, Amarajothi,Concepcion, Patricia,Garcia, Hermenegildo. "Dehydrogenative coupling of silanes with alcohols catalyzed by Cu3(BTC)2". . p. 2725 - 2728. Retrieved 2016.
• 3、 Luconi, Lapo,Rossin, Andrea,Tuci, Giulia,Gafurov, Zufar,Lyubov, Dmitrii M.,Trifonov, Alexander A.,Cicchi, Stefano,Ba, Housseinou,Pham-Huu, Cuong,Yakhvarov, Dmitry,Giambastiani, Giuliano. "Benzoimidazole-Pyridylamido Zirconium and Hafnium Alkyl Complexes as Homogeneous Catalysts for Tandem Carbon Dioxide Hydrosilylation to Methane". . p. 495 - 510. Retrieved 2019.
• 4、 Li, Zhiwen,Lin, Sha,Ji, Lisha,Zhang, Zhonghua,Zhang, Xiaomei,Ding, Yi. "Nanoporous palladium catalyzed silicon-based one-pot cross-coupling reaction of aryl iodides with organosilanes". . p. 1734 - 1737. Retrieved 2014.
• 5、 Yang, Fan,Liu, Zhihui,Liu, Xiaodong,Feng, Andong,Zhang, Bing,Yang, Wang,Li, Yongfeng. "Cobalt single atoms anchored on nitrogen-doped porous carbon as an efficient catalyst for oxidation of silanes". . p. 1026 - 1035. Retrieved 2021/02/09.
• 6、 Liu, Rongjuan,Wei, Jingjing,Wei, Yanze,Yang, Zhijie,Zhang, Fenghua. "Self-Assembled Open Porous Nanoparticle Superstructures". supporting information. . Retrieved 2021/08/20.