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Cas Database

Name	4-(1-Pyrrolidinyl)aniline	EINECS	N/A
CAS No.	2632-65-7	Density	1.109 g/cm³
PSA	29.26000	LogP	2.51520
Solubility	N/A	Melting Point	51 °C
Formula	C₁₀H₁₄N₂	Boiling Point	330.8 °C at 760 mmHg
Molecular Weight	162.235	Flash Point	131.3 °C
Transport Information	N/A	Appearance	N/A
Safety		Risk Codes	N/A
Molecular Structure		Hazard Symbols	N/A
Synonyms	Pyrrolidine,1-(p-aminophenyl)- (6CI,7CI,8CI);4-(Pyrrolidin-1-yl)aniline;4-(Pyrrolidin-1-yl)phenylamine;4-Pyrrolidinoaniline;1-(4-Aminophenyl)pyrrolidine;	Article Data	33

4-(1-Pyrrolidinyl)aniline Synthetic route

: 4-(1-oxy-pyrrolidin-1-yl)-phenylamine

: 2632-65-7
4-pyrrolidin-1-yl-aniline

Conditions

Conditions	Yield
With copper(l) iodide; N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 35 - 40℃; for 3h;	96%

: 10220-22-1
1-(4-nitro-phenyl)-pyrrolidine

: 2632-65-7
4-pyrrolidin-1-yl-aniline

Conditions

Conditions	Yield
With hydrogen In methanol; ethyl acetate at 100℃; for 0.333333h; Flow reactor; Green chemistry; chemoselective reaction;	93%
With ammonium chloride; zinc In tetrahydrofuran; methanol at 0 - 20℃; for 18h;	91.2%
With palladium 10% on activated carbon; hydrogen In ethanol at 20℃; for 9h; Inert atmosphere; Schlenk technique;	85%

: 6574-15-8
1-(4-nitrophenyl)piperidine

: 2632-65-7
4-pyrrolidin-1-yl-aniline

Conditions

Conditions	Yield
With palladium 10% on activated carbon; hydrazine hydrate In ethanol for 12h; Reflux;	80%

: 22090-26-2
1-(4-bromo-phenyl)-pyrrolidine

: 2632-65-7
4-pyrrolidin-1-yl-aniline

Conditions

Conditions	Yield
Stage #1: 1-(4-bromo-phenyl)-pyrrolidine With magnesium In tetrahydrofuran Inert atmosphere; Stage #2: With C10H17NO In tetrahydrofuran; toluene at -78℃; for 2h; Inert atmosphere; Stage #3: With ammonium chloride In tetrahydrofuran; water; toluene Inert atmosphere;	57%

: 123-75-1
pyrrolidine

: 106-40-1
4-bromo-aniline

: 2632-65-7
4-pyrrolidin-1-yl-aniline

Conditions

Conditions	Yield
With cesium hydroxide In dimethyl sulfoxide at 120℃; for 0.166667h;	52%

: 1-(4-nitroso-phenyl)-pyrrolidine; hydrochloride

: 2632-65-7
4-pyrrolidin-1-yl-aniline

Conditions

Conditions	Yield
With hydrogenchloride; tin

: 110-56-5
1,4-dichlorobutane

: 106-50-3
1,4-phenylenediamine

: 2632-65-7
4-pyrrolidin-1-yl-aniline

Conditions

Conditions	Yield
With 1,2-dichloro-benzene at 110℃;

: 109-99-9
tetrahydrofuran

: 106-50-3
1,4-phenylenediamine

A: 2632-65-7
4-pyrrolidin-1-yl-aniline

B: 50771-64-7
1,4-di(pyrrolidin-1-yl)benzene

Conditions

Conditions	Yield
titanium(IV) oxide at 250 - 300℃; Yield given. Yields of byproduct given;

: 100-00-5
4-chlorobenzonitrile

: 2632-65-7
4-pyrrolidin-1-yl-aniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: ethanol 2: nickel-chromium oxide catalyst; methanol / 80 °C / 147102 Torr / Hydrogenation View Scheme
Multi-step reaction with 2 steps 2: Raney nickel; ethanol / 60 °C / 2206.5 Torr / Hydrogenation View Scheme
Multi-step reaction with 2 steps 1: potassium carbonate; Aliquat (at)366 / N,N-dimethyl-formamide / 24 h / 100 °C 2: ammonium hydroxide; sodium dithionite / water / 0.25 h / Reflux View Scheme

: 1258532-14-7
C15H22N2O2

: 2632-65-7
4-pyrrolidin-1-yl-aniline

Conditions

Conditions	Yield
With hydrogenchloride In 1,4-dioxane; dichloromethane at 20℃; for 6h;

4-(1-Pyrrolidinyl)aniline Specification

The Benzenamine,4-(1-pyrrolidinyl)-, with the CAS registry number 2632-65-7, is also known as 4-Pyrrolidinoaniline. This chemical's molecular formula is C₁₀H₁₄N₂ and molecular weight is 162.23. What's more, its systematic name is 4-(pyrrolidin-1-yl)aniline.

Physical properties of Benzenamine,4-(1-pyrrolidinyl)- are: (1)ACD/LogP: 1.13; (2)# of Rule of 5 Violations: 0; (3)#H bond acceptors: 2; (4)#H bond donors: 2; (5)#Freely Rotating Bonds: 2; (6)Polar Surface Area: 6.48 Å²; (7)Index of Refraction: 1.609; (8)Molar Refractivity: 50.69 cm³; (9)Molar Volume: 146.2 cm³; (10)Polarizability: 20.09×10^-24cm³; (11)Surface Tension: 49.8 dyne/cm; (12)Density: 1.109 g/cm³; (13)Flash Point: 131.3 °C; (14)Enthalpy of Vaporization: 57.34 kJ/mol; (15)Boiling Point: 330.8 °C at 760 mmHg; (16)Vapour Pressure: 0.000162 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: c1(ccc(cc1)N2CCCC2)N
(2)InChI: InChI=1S/C10H14N2/c11-9-3-5-10(6-4-9)12-7-1-2-8-12/h3-6H,1-2,7-8,11H2
(3)InChIKey: URAARCWOADCWLA-UHFFFAOYSA-N

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