92851-13-3

Basic information

• Product Name: Carbamic acid, (4-methoxyphenyl)-, phenylmethyl ester (9CI)
• Synonyms: Carbamic acid, (4-methoxyphenyl)-, phenylmethyl ester (9CI);benzyl (4-methoxyphenyl)carbamate(WXC04599)
• CAS NO: 92851-13-3
• Molecular Formula: C₁₅H₁₅NO₃
• Molecular Weight: 257.2845
• Product Categories: N-CBZ
• Mol File: 92851-13-3.mol
• Article Data: 29

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Carbamic acid, (4-methoxyphenyl)-, phenylmethyl ester (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, (4-methoxyphenyl)-, phenylmethyl ester (9CI)(92851-13-3)
• EPA Substance Registry System: Carbamic acid, (4-methoxyphenyl)-, phenylmethyl ester (9CI)(92851-13-3)

Safety Data

• Hazardous Substances Data: 92851-13-3(Hazardous Substances Data)

Upstream product

• 124-38-9 carbon dioxide 
• 100-51-6 benzyl alcohol 
• 3532-17-0 4-methoxybenzoyl azide 
• 104-57-4 benzyl formate 
• 18437-68-8 tert-butyl N-(4-methoxyphenyl)carbamate 
• 100-39-0 benzyl bromide 
• 104-94-9 4-methoxy-aniline 
• 3422-03-5 benzyloxycarbonyl azide 
• 5720-07-0 4-methoxyphenylboronic acid 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 621-84-1 O-benzyl carbamate 
• 10364-93-9 1-(4-methoxybenzoyl)-imidazole 
• 100-09-4 4-methoxybenzoic acid 
• 10507-69-4 4-methoxybenzohydroxamic acid 

Downstream Products

• 26849-50-3 N-(p-methoxyphenyl)-N'-butylurea 
• 1259118-35-8 3-(4-methoxyphenyl)-5-phenyloxazol-2(3H)-one 
• 7472-54-0 N-(p-methoxyphenyl)benzamide 
• 1359874-37-5 benzyl allyl(4-methoxyphenyl)carbamate 
• 1428098-77-4 3-(4-methoxyphenyl)-5-(2,2,3,3,4,4,5,5,5-nonafluoropentyl)oxazolidin-2-one 
• 1428098-66-1 5-(3-chloro-2,2,3,3-tetrafluoropropyl)-3-(4-methoxyphenyl)oxazolidin-2-one 
• 1428098-56-9 benzyl 4-methoxyphenyl(4,4,5,5,6,6,7,7,7-nonafluoro-2-iodoheptyl)carbamate 
• 1428098-45-6 benzyl 5-chloro-4,4,5,5-tetrafluoro-2-iodopentyl(4-methoxyphenyl)carbamate 
• 1428098-92-3 5-(2,2-difluoro-2-(5-phenyl-1,2,4-oxadiazol-3-yl)ethyl)-3-(4-methoxyphenyl)oxazolidin-2-one 
• 1067891-52-4 benzyl 4-methoxyphenyl((2-methyloxiran-2-yl)methyl)carbamate 
• 18437-68-8 tert-butyl N-(4-methoxyphenyl)carbamate 
• 104-94-9 4-methoxy-aniline 
• 5416-93-3 4-Methoxyphenyl isocyanate 
• 100-51-6 benzyl alcohol 

Relevant articles and documents

Interrupted aza-Wittig reactions using iminophosphoranes to synthesize 11C-carbonyls

A direct CO2-fixation methodology couples structurally diverse iminophosphoranes with various nucleophiles to synthesize ureas, carbamates, thiocarbamates, and amides, and is amenable for 11C radiolabeling. This methodology is practical, as demonstrated by the synthesis of >35 products and isolation of the molecular imaging radiopharmaceuticals [11C]URB694 and [11C]glibenclamide. This journal is

PIFA-Promoted, Solvent-Controlled Selective Functionalization of C(sp2)-H or C(sp3)-H: Nitration via C-N Bond Cleavage of CH3NO2, Cyanation, or Oxygenation in Water

A novel nitration (via C(sp3)-N breaking/C(sp2)-N formation with CH3NO2) mediated by [bis(trifluoroacetoxy)iodo]benzene (PIFA) is described. The NO2 transfer from CH3NO2 to the aromatic group of the substrate is possible with careful selection of the solvent, NaX, and oxidant. In addition, the solvent-controlled C(sp2)-H functionalization can shift to an α-C(sp3)-H functionalization (cyanation or oxygenation) of the α-C(sp3)-H of cyclic amines.

One stone two birds: Cobalt-catalyzed in situ generation of isocyanates and benzyl alcohols for the synthesis of N-aryl carbamates

An efficient method for the synthesis of N-aryl carbamates from N-Boc-protected amines has been developed. The cobalt-catalyzed in situ generation of isocyanates from N-Boc-protected amines and benzyl alcohols from benzyl formates has been achieved for the first time, which in turn furnished the corresponding benzyl carbamates in moderate to high yields. The reaction was catalyzed by CoI2 with tris-(4-dimethylaminophenyl)-phosphine as the ligand and zinc powder as the reductant. The developed reaction conditions were found to be compatible for aromatic amines with both electron-donating and -withdrawing substituents.