92591-97-4

Basic information

• Product Name: t-butyl (benzyl 5,6-dideoxy-6-dimethoxyphosphoryl-2,3-O-isopropylidene-α-D-lyxo-heptofuranosid)uronate
• CAS NO: 92591-97-4
• Molecular Weight: 486.499
• Mol File: 92591-97-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: t-butyl (benzyl 5,6-dideoxy-6-dimethoxyphosphoryl-2,3-O-isopropylidene-α-D-lyxo-heptofuranosid)uronate(CAS DataBase Reference)
• NIST Chemistry Reference: t-butyl (benzyl 5,6-dideoxy-6-dimethoxyphosphoryl-2,3-O-isopropylidene-α-D-lyxo-heptofuranosid)uronate(92591-97-4)
• EPA Substance Registry System: t-butyl (benzyl 5,6-dideoxy-6-dimethoxyphosphoryl-2,3-O-isopropylidene-α-D-lyxo-heptofuranosid)uronate(92591-97-4)

Safety Data

• Hazardous Substances Data: 92591-97-4(Hazardous Substances Data)

Upstream product

• 20786-73-6 (6-benzyloxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methanol 
• 62327-21-3 tert-butyl dimethylphosphonoacetate 
• 88165-21-3 benzyl 2,3-O-isopropylidene-5-O-trifluoromethylsulphonyl-α-D-lyxofuranoside 

Downstream Products

• 138-59-0 shikimic acid 

Relevant articles and documents

Enantiospecific Synthesis of Shikimic Acid from D-Mannose: Formation of a Chiral Cyclohexene by Intramolecular Olefination of a Carbohydrate-derived Intermediate

An enantiospecific synthesis of (-)-shikimic acid from D-mannose in an overall yield of 39percent is described, in which the key step is an intramolecular Wadsworth-Emmons olefination reaction of a phosphonate.Nucleophilic displacement of triflate from benzyl 2,3-O-isopropylidene-5-O-trifluoromethylsulphonyl-α-D-lyxofuranoside by the sodium salt of t-butyl dimethoxyphosphorylacetate provides a rare example of substitution at the C-5 position of a furanose derivative by a carbanion.