85908-78-7Relevant articles and documents
PROCESS FOR PREPARING DIENYL-RUTHENIUM COMPLEXES
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Page/Page column 5, (2011/08/06)
The present invention relates to a single-stage process for preparing dienyl-ruthenium complexes of the formula Ru(+II)(dienyl)2, wherein an Ru(II) starting compound of the formula Ru(X)p(Y)q is reacted with a diene ligand in the presence of an inorganic and/or organic base in a single-stage process. Here, polar organic solvents, preferably mixtures of polar organic solvents with water, are used. The dienyl-ruthenium complexes prepared according to the invention are used as precursors for homo-geneous catalysts, for producing functional coatings and for therapeutic applications.
PROCESS FOR PREPARING DIENYL-RUTHENIUM COMPLEXES
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Page/Page column 15, (2009/12/28)
The present invention relates to a single-stage process for preparing dienyl- ruthenium complexes of the formula Ru(+II)(dienyl)2, wherein an Ru(II) starting compound of the formula Ru(X)p(Y)q is reacted with a diene ligand in the presence of an inorganic and/or organic base in a single-stage process. Here, polar organic solvents, preferably mixtures of polar organic solvents with water, are used. The dienyl-ruthenium complexes prepared according to the invention are used as precursors for homogeneous catalysts, for producing functional coatings and for therapeutic applications.
Synthesis and characterization of bis(pentadienyl)ruthenium compounds
Stahl, Lothar,Ernst, Richard D.
, p. 1229 - 1234 (2008/10/08)
The syntheses of bis(2,4-dimethylpentadienyl)ruthenium and bis(2,3,4-trimethylpentadienyl)ruthenium are reported. Characterization was achieved by using infrared, 1H NMR, 13C NMR, and mass spectroscopy, as well as elemental analysis. In both cases, variable-temperature 1H NMR data reveals an unsymmetric ground state with respective barriers to ligand oscillation of 9.73 and 10.16 kcal/mol. A single-crystal X-ray diffraction study of Ru(2,3,4-C8H13)2 has also been undertaken. The space group is Ci1-P1 (No. 2) with a = 9.213 (4) A, b = 11.486 (4) ?, c = 7.811 (4) ?, α = 101.20 (4)°, β = 114.97 (3)°, γ = 91.89 (3)°, Z = 2, and Dcalcd = 1.46 g/cm3. The final R factor was 0.059 for the 2158 independent observed reflections. Despite the fact that two nearly eclipsing CH3?CH3 interactions result, the complex still adopts the gauche-eclipsed conformation in preference to the anti conformation. The complex is characterized by average Ru-C and C-C bond distances of 2.188 (3) and 1.428 (5) ?, respectively. A number of comparisons are made between these structural data and that of ruthenocene as well as other metal pentadienyl and bis(cyclo-η5-dienyl)metal complexes.