2,4-dimethanidylpentane, ruthenium

Base Information

• Chemical Name: 2,4-dimethanidylpentane, ruthenium
• CAS No.: 85908-78-7
• Molecular Formula: C₁₄H₂₂Ru
• Molecular Weight: 291.399
• Hs Code.: 28439000
• Mol file: 85908-78-7.mol

Synonyms:Ruthenium,bis[(1,2,3,4,5-h)-2,4-dimethyl-2,4-pentadienyl]-(9CI); 1,3-Pentadiene, 2,4-dimethyl-, ruthenium complex;Bis(2,4-dimethyl-1,3-pentadienyl)ruthenium;Bis(2,4-dimethylpentadienyl)ruthenium; Bis(h5-2,4-dimethyl-2,4-pentadien-1-yl)ruthenium; Bis(h5-2,4-dimethyl-2,4-pentadienyl)ruthenium;Ruthenium bis(2,4-dimethylpentanediyl)

Chemical Property of 2,4-dimethanidylpentane, ruthenium

Chemical Property:

• Melting Point: 85°C
• PSA: 0.00000
• LogP: 4.81140

Purity/Quality:

97% ^*data from raw suppliers

Bis(2,4-dimethylpentadienyl)ruthenium(II), 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: As volatile ruthenium complex, Bis(2,4-dimethylpentadienyl)ruthenium can be useful for the MOCVD of ruthenium and ruthenium oxide.

Technology Process of 2,4-dimethanidylpentane, ruthenium

There total 7 articles about 2,4-dimethanidylpentane, ruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2,4-Dimethyl-1,3-pentadiene (1000-86-8) + dichloro-bis-μ-chloro-bis[(1-3η:6-8η)-2,7-dimethyloctadienediyl]diruthenium(II) → (η5-2,4-dimethylpentadienyl)2ruthenium(II) (85908-78-7)

Guidance literature:

With Li₂CO₃; In ethanol; acetonitrile; soln. of Ru-complex and 4 equiv. of Li2CO3 in a mixt. of ethanol, 1 equiv. of MeCN and 8 equiv. of ligand were refluxed for 4 h under N2; solvent was evapd., residue was sublimated, elem. anal.;

DOI:10.1021/om0007015

Reference yield: 91.0%

2,4-Dimethyl-1,3-pentadiene (1000-86-8) + {RuCl2(NCMe)4} (30066-40-1,939024-67-6,134001-83-5) → bis(2,4-dimethyl-1,3-pentadienyl)ruthenium(II) (85908-78-7)

Guidance literature:

With sodium carbonate; In water; acetone; at 65 ℃; for 5h; Product distribution / selectivity;

Reference yield: 91.0%

2,4-Dimethyl-1,3-pentadiene (1000-86-8) + RuCl2(acetonitrile)4 → (η5-2,4-dimethylpentadienyl)2ruthenium(II) (85908-78-7)

Guidance literature:

With sodium carbonate; In water; acetone; at 65 ℃; for 5h; Product distribution / selectivity;

upstream raw materials:

2,4-Dimethyl-1,3-pentadiene

ruthenium(III) chloride hydrate

{RuCl₂(NCMe)4}

Refernces

• 1、 -. "High nucleation density organometallic compounds". Page/Page column 18; 19. . Retrieved 2010/03/05.
• 2、 Bauer, André. "Efficient synthesis of ruthenium(II) η5-dienyl compounds starting from Di-μ-chlorodichloro-bis[(1-3η:6-8η)-2,7-dimethyloctadienediyl] diruthenium(IV). Versatile precursors for enantioselective hydrogenation catalysts". . p. 5471 - 5476. Retrieved 2008/10/08.